Silver Acetate Formula: Preparation, Properties and Sample Questions

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Silver Acetate (CH3CO2Ag or AgC2H3O2) is a compound formed by reacting acetic acid with silver carbonate. It can also be prepared from aqueous silver nitrate and an acetate ion. In the physical form, it is found as crystalline solid in white or greyish colour with slightly acidic smell. Silver Acetate is a moderately water-soluble crystalline silver source that decomposes to silver oxide on heating. It is used in the preparation of highly reflective, conductive silvered polymer films. 

Key Terms: Silver Acetate, Compound, Acetic Acid, Silver Nitrate, Crystalline, Oxidation


Silver Acetate Structure and Formula

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Formula of Silver Acetate: CH3CO2Ag or AgC2H3O2

Structure: It is formed from one acetate anion CH3COO- and silver cation Ag+.

silver acetate

Also Read: Calcium Acetate


Silver Acetate Preparation

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Silver acetate can be prepared when acetic acid reacts with the silver carbonate which gives the required product along with water and carbon dioxide.

2 CH3CO2H + Ag2CO3 → 2 AgO2CCH3 + H2O + CO2

The product formed by the reaction needs to be precipitated to get the silver acetate in its true form.

Also Read: Potassium acetate


Properties of Silver Acetate

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Silver acetate is white or greyish in colour and the odour is acidic in nature.

The boiling point of the compound CH3CO2Ag is 220 °C.

Moreover, the density is 3.25 g/cm3.

Silver acetate is not soluble in water properly.

Silver acetate with the compound formula CH3CO2Ag has a molecular mass of 166.92 amu. Molecular mass is calculated as the total of the atomic masses of the elements.

Here, atomic mass of Carbon (C) = 12 amu

atomic mass of Hydrogen (H) = 1 amu

atomic mass of Iodine(O) = 16 amu

atomic mass of Silver (Ag) = 108 amu

So, molecular mass of CH3CO2Ag = 2 × atomic mass of Nitrogen (C) + 3 × atomic mass of Hydrogen (H) + 2 × atomic mass of oxygen (O) + atomic mass of Silver (Ag)

Molecular mass of CH3CO2Ag = 2 × 12 + 3 × 1 + 2 × 16 + 107.92 amu

Molecular mass of CH3CO2Ag = 166.92 amu

The exact mass of CH3CO2Ag is 165.918 amu

Also Read: Methyl Acetate


Things to Remember

  • Silver acetate is from the group of acetate salts.
  • IUPAC name is Silver(I) ethanoate.
  • Silver acetate is a strong acid.
  • Silver ions lacking oxidizing ions in silver acetate have various applications.
  • It is partially soluble in water but completely soluble in dilute HNO3.
  • Approximately two – third of the total composition of silver acetate is of silver.
  • Excess use of silver acetate salt can result as toxic for humans.

Sample Questions

Ques. Is silver acetate organic or inorganic? (2 Marks)

Ans. Organic compounds are the compounds which contain carbon atoms in them whereas in inorganic compounds, the carbon atoms are absent. Organic carbon is found in nature through plants and living things but inorganic carbon is extracted from ores and minerals. Hence, silver acetate has carbon atoms so it is an organic compound.

Ques. Is silver acetate soluble in water? (2 Marks)

Ans. Silver acetate is partially soluble in water but the solubility increases with increase in temperature. At the temperature 20 °C, the amount of silver acetate soluble in 100 g of water is about 1.2 g. But when the temperature is raised to 80 °C then the solubility of silver acetate also increases to 2.52 g in the same amount of water.

Ques. What is the percent composition of elements in silver acetate? (2 Marks)

Ans. Silver Acetate (CH3CO2Ag or AgC2H3O2) is a compound which is the combination of four elements i.e., carbon, hydrogen, oxygen and silver in different compositions. The dominant element with highest percent composition in silver acetate is silver (Ag) with 64.63% followed by oxygen with 19.17%. Other two elements, carbon and hydrogen are 14.39% and 1.81% respectively in silver acetate.

Ques. What is the other method to prepare silver acetate? (3 Marks)

Ans. Silver acetate is prepared by acetic acid reacting with silver carbonate. Apart from this, silver acetate can also be prepared by mixing the two concentrated solutions of the silver nitrate (AgNO3) with sodium acetate (CH3COONa).

CH3COONa + AgNO3 CH3COOAg + NaNO3

The resultant product is the combination of silver acetate and sodium nitrate. In the solution, silver acetate is found in the form of precipitates. So, wash it and dry the poorly soluble silver acetate.

Ques. What are the uses of silver acetate? (2 Marks)

Ans. Silver acetate is commonly used as pesticides because of the property of photosensitivity. Also, it produces a repulsive taste when combined with cigarette smoke, so it is used in chewing gum and lozenges to aid the cessation of smoking. Moreover, it is photosensitive and is an important reagent used in the laboratory because of the silver ions which are lacking in oxidizing anions. It is used in the preparation of highly reflective, conductive silvered polymer films.

Ques. Is silver acetate toxic? (3 Marks)

Ans. Silver salts are considered to be toxic to humans as silver and its compounds contained in salts are absorbed into the circulatory system and become deposited in various body tissues if large doses are taken which leads to disease called argyria. The disease is a blue grey discolouration of the skin and other body tissues. 

It is a permanent effect but does not appear to be harmful to health. Exposure to high levels of silver in the air has resulted in breathing problems, lung and throat irritation, and stomach pains. Skin contact with silver can cause mild allergic reactions such as rash, swelling, and inflammation in some people.

Ques. When silver acetate reacts with methyl bromide gives.
Acetic acid
Methyl acetate
Acetyl bromide
Acetaldehyde (2 Marks)

Ans. (b)

Explanation: When methyl bromide reacts with the silver acetate, the latter will split into the ions i.e., positive part is silver and negative part is acetate. So, the acetate will attack the positive ethyl group of the methyl bromide and result in the formation of the methyl acetate.

CH3Br + CH3COOAg → CH3COOCH3 + AgBr

Ques. What happens when silver acetate is heated? (2 Marks)

Ans. The boiling point of the compound CH3CO2Ag is 220 °C. Silver acetate decomposes when heated to give organic side products along with the main products like acetone, carbon dioxide, oxygen and silver metal. Also, some traces of water are found after heating the compound.

2 CH3COOAg → 2 Ag + (CH3)2CO + CO2 + ½ O2

Ques. Is silver acetate an acid or base? (2 Marks)

Ans. Silver acetate is classified as a strong acid. They are characterised as the class of organic compounds known as acetate salts. Acetate is type of salt which is formed by the combination of acetic acid with some base. These are organic compounds containing acetic acid as its acid component. The chemical formula of acetate salts is C2H3O2-.

Ques. How can metal silver be separated from silver acetated? (2 Marks)

Ans. Hydrogenation is a type of chemical reaction in which the molecular hydrogen reacts with the other compounds or elements in presence of some catalyst such as nickel, palladium or platinum. So, solution of silver acetate in pyridine reacts with the molecular hydrogen and produces the required metal silver.

2 CH3CO2Ag + H2 → 2 Ag + 2 CH3CO2H

Also Read:

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