Write short notes on the Atomic spectra or line spectra.

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The spectrum, which plural form is spectra refers to the distribution of energy as a function of wavelength or frequency. Spectra is used to study the structure and composition of matter and provide information about the energies of the atoms and molecules in a sample.

Line Spectra or Atomic Spectra: The spectrum of electromagnetic radiations emitted or absorbed by electrons during the transition between different energy levels is called Atomic Spectra or Line Spectra.

  • It consists of sharp and well-defined lines
  • It is characteristic of atoms
  • It is formed due to the excitation and de-excitation of electrons in the atoms

Atomic Spectra are classified into two types:

  1. Emission Spectra or Line Emission spectra
  2. Absorption spectra or Line Absorption spectra

Emission Spectra: When an atomic gas or vapor is excited at low pressure by passing an electric current through it, the emitted radiation has a spectrum that contains a specific wavelength, is termed Emission spectra, and consists of bright lines on a dark background.

  • It is also known as a line emission spectra.
  • The spectrum obtained is distinct and discontinuous.

Absorption spectra: When white light passes through atomic gas or vapor, then the spectrum of transmitted light is observed with a spectrometer showing some dark lines which replaces some bright lines seen in the emission spectrum of the gas. This type of spectra is known as Absorption spectra.

  • It is also known as line absorption spectra
  • The spectrum obtained is continuous with dark lines

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CBSE CLASS XII Related Questions

  • 1.

    (a) Write two structural differences between DNA and RNA.

    (b) Which component of starch is a branched chain polymer of \( \alpha \)-D-(+)-glucose ? Write its one characteristic feature.

    (c) Which types of bonds hold the polypeptide chains in fibrous proteins ?


      • 2.
        An organic compound (X) has the molecular formula \(C_5H_{10}O\). Draw structures for (X) if it:
        (I) does not give Tollen's test but gives a positive iodoform test.
        (II) does not give Tollen's test and iodoform test but undergoes Aldol condensation.
        (III) undergoes Cannizzaro's reaction.


          • 3.
            From the given data of \(E^{\circ}\) values, answer the following questions :
            (I) Why \(E^{\circ}_{M^{2+}/M}\) show irregular trend in the above values ?
            (II) Why is \(E^{\circ}_{Cu^{2+}/Cu}\) value exceptionally positive ?
            (III) Why \(E^{\circ}_{Mn^{2+}/Mn}\) value is highly negative ?


              • 4.

                (i) Why do Zr and Hf exhibit similar properties ?

                (ii) "\( E^\circ \) for \( \mathrm{Mn^{3+}/Mn^{2+}} \) couple is more positive than that for \( \mathrm{Fe^{3+}/Fe^{2+}} \)." Justify the statement.

                [Atomic number : Mn = 25, Fe = 26]


                  • 5.
                    Following reaction takes place in one step:

                    \(2A + B \rightarrow 2C\)

                    How will the rate of above reaction change if the volume of the reaction vessel is decreased to one third of its original volume? Will there be any change in the order of reaction with the reduced volume?


                      • 6.

                        Explain the Finkelstein reaction.

                          CBSE CLASS XII Previous Year Papers

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