Molar Mass: Formula, Molar Mass Unit & Percentage

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Molar mass, in chemistry, is defined as the mass of a sample divided by the amount of substance in the sample, measured in moles.

  • The term mole refers to the atomic mass of a molecule measured in grams. Atomic mass is the mass of a single atom and molecular mass is the mass of a group of atoms.
  • The mole concept summarizes the mass of a single atom or molecule into a unit. ‘U’ refers to the mass of a large group of comparable molecules in grams.
  • The number of units in a mole is the amount of a substance that is exactly 6.02214076 × 1023 (a fundamental constant known as Avogadro's number or Avogadro's constant)" Elemental Units" of this substance.
  • For individual elements or individual atoms, the molar mass is simply the mass of the element expressed in atomic mass units.
  • The atomic mass and the molar mass of a single atom are exactly the same.
  • Since the molar mass and the atomic mass are identical for individual atoms, the molar mass can be used to measure the identity of a particle

Read Also: Atoms & Molecules

Key Terms: Molar Mass, Relative Molecular Mass, Molecular Weight, Avogadro Constant, Percentage Of Composition

Read Also: Atomic And Molecular Masses


What is Mole?

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A mole can be defined in chemistry as: 

"Amount of a substance containing exactly 6.02214076 × 1023 'elementary units' of a given substance" 

  •  The word "mole" was introduced around 1896 by the German chemist Wilhelm Ostwald, The term derived from the Latin word moles, meaning "heap" or "heap". 
  •  The number of moles of a molecule cannot always be equal to the number of moles of its constituents. 
  •  For example, one mole of water contains Na the number of molecules of H2O. However, each water molecule contains 2 hydrogen atoms and one oxygen atom. Therefore, one mole of H2O contains 2 moles of hydrogen and one mole of oxygen.

What is Molar Mass?

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The "mass per mole" can be used to describe the molar mass. In other words, the molar mass is the sum of the masses of all the atoms of a substance, expressed in moles. It is expressed in the unit grams per mole.

  • Elements and molecules are represented by their molar mass. For individual elements or atoms, the molar mass is simply the mass of the element, expressed in atomic mass units.
  • For example, the atomic mass of helium is 4. Since it has only one atom and is monatomic in nature, helium has a molar mass of 4.
  • The molar concept facilitates the macroscopic representation of quantitative information about the processes occurring in a chemical equation.
  • In the chemical reaction 2H2O = O2 + 2H2, two moles of water are broken down into two moles of molecular hydrogen and one mole of molecular oxygen.
  • The mole can be used to determine the simplest formula of a compound and the amounts required for chemical reactions. 
  • The related concept of molarity is useful when dealing with reactions that occur in solutions.
  • The number of moles of a solute in a liter of solution is called its molarity (M).

Molar Mass Formula 

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To make measurements of mass useful we must express chemical quantities at the macroscopic level. 

The bridge between the particulate and the macroscopic levels is molar mass, the mass in grams of one mole of a substance. the units of molar mass follow its definition; grams per mole. Mathematically, the defining equation of molar mass is:

Molar Mass = Mass/Mole = G/Mol

The definition of atomic mass, the mole, and molar mass are all directly or indirectly related to carbon-12. Thus,

  • The mass of one atom of carbon-12 atomic mass of carbon-12 is exactly 12 atomic mass units.
  • The molar mass or molecular weight which is the sum of the total mass in grams of all the atoms that make up a mole of a molecule. 

Units of Molar Mass

The unit of molar is as follows:

Kg/ Mol Or Gm/Mol

And The S.I. Unit For Mole Is Kg·mol-1.

There Are Some Formulas For Understanding Mole Concept :

  •  Mass Of 1 Mole Of Atoms = Ar In Grams
  •  Number Of Moles Of Atoms = Mass Of The Element In Grams/ Relative Atomic Mass, Ar
  •  Mass Of 1 Mole Of Molecules = Mr In Grams
  •  Number Of Moles Of Molecules =. Mass Of The Substance In Grams/ Relative Molecular Mass (Mr)
  •  Mass Of Substance Containing 1 Mole Of Particles - Molar Mass 
  •  Percentage Yield: Actual Mass Of Product Obtained /Theoretical Mass Of Product Obtainable

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Percentage Of Composition

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The relative amounts of each element in a compound are shown by the percentage composition. Divide the mass of the entity present in the substance by the substance's total mass to determine the percentage of composition.

%CE\(\frac{g^E}{g^T}\) x 100

In this case, 

  • %Ce denotes the compositional percentage of element E. 
  • Ge denotes the total amount of element E in the compound. 
  • Gt denotes the total amount of all the elements present in the compound.

To show the ratio in percentage terms, it is multiplied by 100.

Read Also: Measurement Of Mass And Weight

Calculation Of Molar Mass 

The molar mass of a compound is calculated by adding the quality atomic masses (in g/mol) of the constituent atoms. Suppose the mass of gold is 196.96 amu or 196.96 g/mol. In 196.96 grams of gold, there’s one mole or 6.022 x 1023 gold atoms.

Read Also: Difference Between Element And Compound


Things To Remember 

  • Molar mass is the mass of a given substance divided by the quantity of the particular substance.
  • Molar Mass Formula is given as Molar Mass = Mass Of Given Substance / Amount Of Substance.
  • The S.I. Unit For Molar Mass is Kg/Mol.
  • The number .6.02214076 × 1023 mol-1 is popularly known as the avogadro constant.
  • The atomic mass of an element is the mass of one atom of the element expressed in atomic mass units (amu).

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Sample Questions

Ques: How many moles are in a mole? (2 marks)

Ans: The mole is the chemical quantity unit. A mole is defined as the amount of a substance that contains exactly 12.046 × 1023 ‘(a basic constant known as Avogadro's Number or the avogadro constant) elementary entities’ of the given substance.

Ques: What is a molar mass unit? (1 mark)

Ans: The molar mass or molecular weight which is the sum of the total mass in grams of all the atoms that make up a mole of a molecule. 

units of molar mass: kg/ mol or gm/mol.

Ques: How many numbers of electrons in a mole of Hydrogen molecule? (2 marks)

Ans: The no. of electrons in a mole of the hydrogen molecule is 1 mole of H2 contains 6.023 × 1023 molecules and each molecule of Hcontains two electrons.

1 mole = 6.022 × 1023 

Therefore, the total no. of electrons in one mole of H2 is 12.046 × 1023.

Ques: What is the molar mass of Calcium Carbonate CaCO3? (3 marks) 

Ans: We know that:

Molar mass = Mass of Given Substance/Amount of Substance

In case of calcium carbonate that contains one atom of Calcium, one atom of Carbon and Three atoms of oxygen. 

Molecular weight for Ca is 40, C is 12.01, O is 16.00 (as per periodic table)

When we add up the total values i.e. 

1x40 + 1x12 + 3x16 = 100

Therefore, the molar mass of CaCO3 is 100 g/mole

Ques: Identify the molar mass of Calcium Nitrate, Ca(NO3)2(3 marks) 

Ans: We know that:

Molar Mass = Mass of Given Substance/Amount of Substance

The total no of atoms for calcium nitrate are as follows:

one atom of calcium, two atoms of nitrogen and six atoms of oxygen.

Molecular weight for Ca is 40, N is 14, O is 16.00 (as per the periodic table)

Ca: 1 x 40.1 = 40.1

N: 2 x 14.0 = 28

O: 6 x 16.0 = 96

If we add all, 40.1 + 14 + 16 = 164.1

Therefore, Ca(NO3)2 has 164.1 g/mol of molar mass.

Ques: What is the molar mass of Potassium oxide? (2 marks)

Ans: The chemical formula of potassium oxide is K2O.

It contains two potassium atoms and one oxygen atom. We know that the molecular weight of Potassium (K) is 39.1 g/mol, and oxygen (o) is 16 g/mol. 

Therefore, the molar mass of potassium oxide is

k = 2 × 39.1 = 78.2 g/mol.

o = 1 × 16 = 16 g/mol.

By adding all we get = 78.2 + 16 = 94.2

Therefore, the molar mass of K2O is 94.2 g/mol. 

Ques: What is the molar mass of sodium azide? (2 marks)

Ans: The chemical formula of Sodium Azide is NaNO3

It contains one sodium atom, and three nitrogen atoms of Nitrogen. We know that the molecular weight of Sodium (Na) is 22.98g/mol, and Nitrogen (N) is 14.0067 g/mol.

Therefore, the molar mass of sodium azide is

Na= 1 × 22.98 = 22.98 g/mol.

N = 3 × 14.0067 = 42 g/mol.

By adding all we get = 22.98 + 42 = 64.98. Therefore, the molar mass of NaNO3 is 64.98 g/mol.

Ques: Calculate the percentage composition of calcium present in calcium silicate? (5 marks)

Ans:The chemical formula of calcium silicate is CaSiO3.It contains a molecule of calcium, 1 molecule of silicon and 3 molecules of oxygen.

1 mole of calcium has a molar mass of 40.07 grams.

1 × 40.07 = 40.07 grams.

1 mole of silicon has a molar mass of 28 grams.

1 × 28 = 28 grams.

1 mole of oxygen has molar mass of 16 grams

3 × 16= 48 grams.

total molar mass of calcium silicate = 40.07 +28 + 48= 116.07 g/mol.

formula of percentage composition,

%CE\(\frac{g^E}{g^T} \times 100\)

percentage composition of calcium = (40.07/116.07) ×100 = 34.5 %.

Therefore, the percentage composition of calcium is 34.5 %.

Ques: Calculate the percentage composition of aluminium present in Aluminum Nitrate. (5 marks)

Ans: The chemical formula of aluminum nitrate is al (NO3)3. It contains 1 molecule of aluminum, 3 molecules of nitrogen and 9 molecules of oxygen.

1 mole of aluminum has a molar mass of 26.98 grams.

1 × 26.98 = 26.98 grams.

1 mole of nitrogen has a molar mass of 14.01grams.

3 × 14.01= 42.03 grams.

1 mole of oxygen has molar mass of 16 grams

9 × 16= 144 grams.

Total molar mass of aluminum nitrate = 26.98 +42.03 + 144 = 213.01 g/mol.

Formula of percentage composition,

\(C_E = \frac{g^E}{g^T} \times 100\)

Percentage composition of aluminum = (26.98/213.01) ×100 = 12.66 %.

Therefore, the percentage composition of aluminum is 12.66 %

Ques : Find the mass % of composition for bicarbonate of soda (sodium hydrogen carbonate) NaHCO3? (5 marks)
Find the mass percentages (mass %) of Na, H, C, and O in sodium hydrogen carbonate.
atomic mass for Na is 22.99, H is 1.01, C is 12.01, and O is 16.00 (as per the periodic table)

Ans : We will determine each element present in one mole of NaHCO3:

1 mole of Na has a molar mass of 22.99 g 

1 x 22.99 = 22.99 g

1 mole of H has a molar mass of 1.01 g

1 x 1.01 = 1.01 g

1 mole of C has a molar mass of 12.01 g

1 x 12.01 =12.01g

1 mole of oxygen has a molar mass of 16 grams

3 x 16.0 = 48.00 g 

the mass of one mole of NaHCO3 is:

22.99 g + 1.01 g + 12.01 g + 48.00 g = 84.01 g

we know, %\(C_E = \frac{g^E}{g^T} \times 100\)

Mass percentages of the elements are:

mass % for Na = 22.99 g / 84.01 g x 100 = 27.36 %

mass % for H = 1.01 g / 84.01 g x 100 = 1.20 %

mass % for C = 12.01 g / 84.01 g x 100 = 14.30 %

mass % for O = 48.00 g / 84.01 g x 100 = 57.14 %

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