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Potassium argon dating, uranium-lead dating and radiocarbon dating come under the category of Radiometric dating. We can get significant information about the ages of fossils and rocks and also the rate of evolution through this method. Potassium Argon (K-Ar) dating method is widely used for measuring the ages of crustal geological processes. The K-Ar method is based on the relative amounts of radioactive atoms. Here, the method is based on rocks of decay of radioactive potassium-40 to radioactive argon-40. This potassium-40 decays to calcium-40. The potassium-argon dating method measures the age sample of objects like meteorites, volcanic rocks, types of minerals, etc. The potassium argon dating method is used in measuring a variety of ages. Developed in the year the 1950s, it was important in developing the theory of plate tectonics and in the calibration of geologic time scales.
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Key Terms: Potassium, Argon, minerals, decay, rocks, radioactive dating, Potassium Argon Dating
Potassium Argon Dating
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Potassium argon dating method or process is used to measure the time of origin of rocks by the ratio of radioactive argon to radioactive potassium in the rocks. This method is used in finding the age samples. Here the element used is potassium, which is a reactive metal and argon is an inert gas. 40K decays to become 40Ar at a given rate, its half-life is about 13000 million years. Geologists and archaeologists used this method to date the rocks as much as 4 billion years old.

Potassium Argon Dating Process
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Potassium Argon Dating Formula
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The decay profile of radioactive potassium defines the age and the origin of radioactive argon. Also, the radioactive potassium decays to radioactive calcium. Usually, the radioactive forms of potassium and argon are potassium-40 and argon-40. The ratio between the radioactive form of potassium, argon, and calcium is measured. It is then compared to the radioactivity time. Hence, the rock age or sample can be measured with this formula.
Working of Potassium Argon Dating
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Potassium (k) is one of the rich elements in the earth’s crust (2.4% by mass). Radioactive potassium is one of the 10,000 potassium atoms present. Every atom has 19 protons and 21 neutrons in its nucleus. If one of these protons gets hit by a beta particle, it can be converted into a neutron. After that 18 protons and 22 neutrons, the atom has become Argon-40, an inert gas. For every 100 K-40 atoms that decay, 11 become Ar-40. When the rocks get heated at a particular melting point, the Ar-40 is released into the atmosphere. When the rocks get recrystallized, it becomes impermeable to other gases again. By observing the conversion of potassium into argon, the age of the rock or sample can be found.

Decaying of Potassium
The most important factor on which the potassium argon dating is dependent is Radioactivity. With the transformation of elements like radioactive potassium into radioactive argon, the age of the sample can be observed. Every radioactive element has its own particular life span.
Limitations of Potassium Argon Dating
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As this method is geological and archaeological, there are some limitations to the method. The limitations are as given below:
- The sample rocks or volcanic rocks don’t have evidence of going through the heating recrystallization method after initial formation. For this, a team of expert geologists is needed to study the entire method. If there is any defect in the observation it can create problems in observation.
- The sample for rocks are taken as per time duration. So, the time duration of the sample should be measured and observed correctly.
- If the sample is more than one million years old, it becomes difficult to find the actual origin and age. So, the ratio of radioactive potassium and radioactive argon atoms present in the sample should be mentioned properly.
Things to Remember
- Potassium argon dating process is the oldest method of dating decayed old rocks or materials. This method is used to measure the origin of rocks by the ratio of radioactive potassium to radioactive argon.
- The method is based on the radioactive isotope of Potassium, Potassium-40(K-40) decays to argon, Argon (Ar-40).
- Most important factor which plays important role in potassium argon dating is radioactivity.
- The potassium argon dating method is dependent on the richness of nonradioactive calcium, potassium and argon in the earth.
- Many meteorites have been dated back to 4 million years through this method of dating of objects.
- To get accurate results the observation of time duration is important for this dating method.
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Sample Questions
Ques. What is radioactivity? Mention its types. (3 marks)
Ans. Radioactivity is the process of the nuclear phenomenon in which decay of the unstable nucleus takes place. It has two forces, one is the attraction forces of the nucleus and another is the force of repulsion, which helps the nucleus be together. There are three types of nuclear decay, they are:
- Alpha (α) decay: Helium is emitted.
- Beta (β) decay: Electrons are emitted.
- Gamma (γ) decay: High energy of protons are emitted.
Ques. Explain the Potassium Argon Dating. (3 marks)
Ans. The Potassium Argon Dating method or process is used to measure the time of origin of rocks by the ratio of radioactive argon to radioactive potassium in the rocks. This method is used in finding the age samples. The potassium argon dating (K-Ar) method is based on the relative amounts of atoms of radioactive. The method is based on rocks of decay of radioactive potassium-40 to radioactive argon-40. This potassium-40 decays to calcium-40.
The most important factor on which potassium-argon dating is dependent is radioactivity. Through the transformation of elements like radioactive potassium into radioactive argon, the age of the sample can be observed. The ratio between radioactive potassium, argon, and calcium is measured. Comparison is made with radioactivity time.
Ques. Give the advantage of potassium argon dating. (3 marks)
Ans. Potassium-argon dating has the basic advantage that argon is an inert gas so it does not react chemically and is not expected to be included in the solidification of rock. Since the argon escapes from the rock, it melts. As potassium occurs as 3 isotopes. The radioactive potassium-40 decays to two by beta decay to 40Ca and by electron capture to 40Ar. Potassium is consistent with many common minerals and comes with a tiny fraction of radioactive K-40.
Ques. What is radioactivity decay? Explain its types. (5 marks)
Ans. Radioactive decay is the method caused due to radiation of emitting energy from an unstable atomic nucleus. There are three most common types of radioactivity decay. They are alpha decay (α-decay), beta decay (β-decay), and gamma decay (γ-decay). The alpha and gamma are governed by electromagnetic forces whereas, beta decay is governed by weak forces. Alpha decay is a method, where a nucleus emits an alpha particle (helium nucleus). Alpha decay formula is given below:
E = (mi − mf − mp) c2
Where,
mi = initial mass of the nucleus
mf = mass of the nucleus after alpha particle emission
mp = mass of the emitted alpha particle
Beta decay is a method, where a beta particle is emitted from an atomic nucleus. Following is an example of it:
234Th90 → 234Pa91 + 0e-1
When the nucleus' high energy level transforms to a lower energy level, the emission of photons has MeV energy, it is called gamma-ray.
Ques. Give examples of nuclear forces. (3 marks)
Ans. The nuclear force is used in different fields. Following are included examples:
- In nuclear power plants, nuclear force generates energy, like electricity.
- Radiocarbon Dating nuclear forces are used for origin
- The fusion process of Hydrogen into Helium in the Sun.
- Holding the nucleus together forces of nuclear play an important role
- Nuclear weapons cause huge destruction to the areas because they release a huge amount of energy.
Ques. Find the energy equivalent of one atomic mass unit, first in Joules and then in MeV. After using this, find the mass defect of 16O8 in MeV/c2. (5 marks)
Ans. 1u = 1.6605 × 10–27 kg
To convert it into energy units, we multiply it by c2 and find that
energy equivalent = 1.6605 × 1027 × (2.9979 × 108)2 kg m2/s2
= 1.4924 × 1010 J
= 1.4924 × 1010 / 1.602 × 1019 eV
= 0.9315 × 109 eV
= 931.5 MeV
or, 1u = 931.5 MeV/c2
For 16O8, ∆M = 0.13691 u = 0.13691 × 931.5 MeV/c2
= 127.5 MeV/c2
The energy needed to separate 16O8 into its constituents is thus 127.5 MeV/c2.
Ques. What are isotopes? Explain its types. (5 marks)
Ans. Isotopes are chemical variants of particular elements which have the same atomic number but a different molecular mass number. Here the difference in mass number is due to the presence of a different number of neutrons. So, the isotopes are variants that have the same number of protons and electrons but different numbers of neutrons in particular elements. There are a total of three types of isotopes:
- Stable isotopes: These isotopes are defined as the isotopes which have long half-lives (half-life is mainly a period in which the compound undergoes decomposition). Examples:
- Carbon: Carbon-12, Carbon-13
- Oxygen: Oxygen-16, Oxygen-17, Oxygen-18
- Primordial isotopes: These isotopes possess primordial nuclei. These primordial nuclides have existed since our solar system was formed. As said that there are 339 naturally occurring isotopes on our earth. Out of 339 remaining 286 isotopes are primordial in nature.
- Radioactive isotopes: Due to radioactive waves there are certain isotopes that have short lives and get decay rapidly by the emission. They are known as radioactive isotopes. Examples:
- Chlorine: Chlorine-36
- Uranium: Uranium-235 and Uranium-238
Ques. Explain the atomic reactor and draw its diagram. (3 marks)
Ans. The atomic reactor is a device used to initiate and control nuclear fission chain reactions or nuclear fusion reactions. The main work of this reactor is to control nuclear fission, where atoms split and release energy. From the given diagram the parts of the reactor can be identified as:
- Fuel Fissionable materials like 92U235, 92U238, and 94U239 are used for fuel.
- To slow down fast neutrons, Moderator Heavy water, graphite and beryllium oxide are used.
- Coolant: The virus water, fluid oxygen, and others are used to eliminate heat produced in the parting interaction.
- Control bars: Cadmium or boron poles are used to safeguard neutrons to control the parting response.

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