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Barium hydroxide is a type of chemical compound, it is also called baryta or baryta-water. Its Chemical Formula is Ba(OH)2. Its physical properties include its appearance being as a clear white powder that is in its commercial form and has no odour. It is also considered poisonous. The nature of this compound is found to be ionic. It is used as a reagent for the metalization of carboxamides. It is also less degradative to barium oxide.
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Structure of Barium Hydroxide
The chemical formula of Barium Hydroxide is Ba(OH)2. So according to that, it should contain only One Barium and Hydroxide each, however, to make the compound neutral we have to add another hydroxide molecule to the compound as Barium and Hydroxide have an unequal number of ions.

Barium Hydroxide
Properties of Barium Hydroxide
There are various physical properties of Barium Hydroxide, these properties are listed below:
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Molar Mass of Barium Hydroxide
The molar mass of Barium Hydroxide can be calculated by adding up the masses of its components. The molar mass of Barium is 137.33 and the molar mass of hydrogen is 1.008. The molar mass of oxygen is 15.999. By adding up all the numbers correctly, we get the molar mass of Barium Hydroxide, which is 171.344g/mol.
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Basicity
Barium Hydroxide is a strong base as it gives out a large number of hydroxide ions when it reacts with water.
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The Melting Point of Barium Hydroxide
The melting point of Barium Hydroxide changes depending upon the level of water it is added to. The octahydrate form, monohydrate form and anhydrous form melt 78-degree celsius, 300-degree Celsius and 407-degree celsius, respectively.
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Solubility
Barium Hydroxide has low solubility in water. A Molar Concentration of 0.1 M is needed to dissolve it in water.
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Boiling Point
Barium Hydroxide boils at 780-degree celsius and decomposes to form barium oxide at 800-degree celsius.
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Colour
The colour of Barium hydroxide is white.
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Appearance
Its appearance is of granular solid.

Barium Hydroxide
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Odour
It has no odour.
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pH Level
Its pH level is 11.27
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Density
The density of the monohydrate form and octahydrate form is 3.74 g/cubic cm and is 2.18 g/cubic cm, respectively.
- It has 3 covalently bonded units.
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Vapour Pressure
Its vapour pressure is 0.48 kPa at 17.6 deg C.
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Reactions of Barium Hydroxide
- Barium hydroxide decomposes into barium oxide when heated to 800 ° C.
- Barium carbonate is obtained by reacting with carbon dioxide.
- It is a strong base so it neutralizes with acid.
- It forms barium sulphate and barium phosphate with sulfuric acid and phosphoric acid, respectively.
- Barium sulfide is produced by the reaction with hydrogen sulfide.
- The reaction between barium hydroxide and ammonium salt is strongly endothermic
- The reaction of barium hydroxide monohydrate with ammonium chloride or ammonium thiocyanate produces enough temperature to freeze the water and enough water to dissolve the resulting mixture.
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Uses of Barium Hydroxide
- It is used to form a strong caustic base in aqueous solutions and is used for a test for sulphides in pesticides or it is also used for the manufacture of glass and alkali.
- Barium hydroxide lime is used instead of soda-lime as it has high sevoflurane concentration, fresh absorbent use and high absorbent temperature.
- It is also used for the manufacture of glass, alkalis, oil and grease additives, other barium compounds and barium soaps.
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Health Hazards Caused By Barium Hydroxide
- Inhalation of barium dust can cause inflammation of the upper respiratory tract and the nose, which leads to benign pneumoconiosis, also known as baritosis.
- They are toxic to the muscles in our body, especially the heart, as they cause irritation and subsequently paralyse the victim.
- It is a very dangerous neurotoxin. Its Side effects include heart and central nervous system (CNS) function dysfunction.
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Things to Remember
- Barium hydroxide is a type of chemical compound, it is also called baryta or baryta-water. It's Chemical Formula is Ba(OH)2. It is also considered poisonous. The nature of this compound is found to be ionic. It is used as a reagent for the metalization of carboxamides. It is also less degradative to barium oxide.
- The chemical formula of Barium Oxide is Ba(OH)2. So according to that, it should contain only One Barium and Hydroxide each, however, to make the compound neutral we have to add another hydroxide molecule to the compound as Barium and Hydroxide have an unequal number of ions.
- Inhalation of barium dust can cause inflammation of the upper respiratory tract and the nose, which leads to benign pneumoconiosis, also known as baritosis. They are toxic to the muscles in our body, especially the heart, as they cause irritation and subsequently paralyse the victim.
- It is used to form a strong caustic base in aqueous solutions and is used for a test for sulphides in pesticides or it is also used for the manufacture of glass and alkali.
- Barium hydroxide decomposes into barium oxide when heated to 800 ° C. Barium carbonate is obtained by reacting with carbon dioxide. It is a strong base so it neutralizes with acid. It forms barium sulphate and barium phosphate with sulfuric acid and phosphoric acid, respectively.
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Sample Questions
Ques: What is the use of barium hydroxide? (3 marks)
Ans: Industrially, barium hydroxide is used as a precursor for several other barium compounds. The monohydrate of this compound is widely used to dehydrate and extract sulfates from a variety of products. This application uses the very low solubility of barium sulphate.
Ques: How is barium hydroxide prepared? (3 marks)
Ans: Barium hydroxide is prepared by dissolving barium oxide in water. The reaction is shown below.
BaO + 9H2O → Ba(OH)2 . 8H2O
It can be seen that this compound crystallizes in the form of octahydrate and is converted to monohydrate by heating in the air.
Ques: What happens when I heat barium hydroxide? (2 marks)
Ans: When heated to 800 ° C, barium hydroxide decomposes to produce barium oxide. Barium carbonate is obtained by reacting with carbon dioxide. A strong alkaline aqueous solution neutralizes with an acid.
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Ques: What is barium hydroxide made of? (2 marks)
Ans: Barium hydroxide is composed of barium cations and hydroxide cations. However, it is manufactured using barium oxide and water.
Ques: Is barium hydroxide ionic? (2 marks)
Ans: Barium hydroxide is ionic. It is composed of Ba2 cation and OH cation. Therefore, there is no way to neutralize the compound. Increase the OH number to 2 to neutralize the compound.
Ques: What are the most important properties of barium hydroxide? (4 marks)
Ans: The most important properties of barium hydroxide are:
- It's white in colour.
- It is a solid grain compound. The density of the form of barium hydroxide monohydrate is 3.74 g / cubic centimetre. The density of the octahydrate form is 2.18 g / cubic centimetre.
- Its molar mass is 171,344 g / mol.
- Its melting points are 78 ° C (for octahydrate), 300 ° C (for monohydrate), and 407 ° C (for anhydrous).
- Its boiling point is 780 ° C. The pH of barium hydroxide is 11.27.
- Slightly soluble in water. Only 0.1M barium hydroxide can be dissolved in water.
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Ques: What is the use of barium hydroxide? (3 marks)
Ans: Barium hydroxide is used at home. In the laboratory, it is used to make other barium products. This compound is used to measure the concentration of weak acids. The name of this process is titration. It is also used for wastewater treatment. This compound is also used in the preparation of glass, grease and alkalis.
Ques: Is barium hydroxide safe? (2 marks)
Ans: Barium hydroxide is corrosive due to hydroxides and can damage the skin and eyes. Prolonged inhalation of barium hydroxide can cause respiratory problems. Therefore, care must be taken when handling barium hydroxide.
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