Copper(II) Chloride(CuCl2): Formula, Structure, Properties and Uses

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Namrata Das

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Copper (II) chloride, also referred to as Cupric chloride, or Copper dichloride, or Cupric dichloride, is a chemical compound with the formula CuCl2. Copper dichloride takes place naturally as an anhydrous mineral called tolbachite and dehydrated eriochalcite. Both are mostly obtained from fumaroles. When it comes to copper dichloride, it starts off light brown and gradually absorbs moisture to become a bluish-green dihydrate. Here, we will discuss more about the chemical compound along with some important questions.

Key takeaways: inorganic salts, chemical synthesis, molecular mass, methanol, ethanol, acetone, oxidising substance


What is Copper Chloride?

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Cupric chloride is another name for copper (II) chloride. It is also an inorganic salt. In chemical synthesis, this salt is also used as a catalyst. For the blue/green colour of this salt, we also employ Copper (II) chloride in the manufacture of pyrotechnics. The formula for Copper II chloride will assist us in learning more about this inorganic salt.

Copper Chloride
Copper Chloride

Formula and Structure of Copper Chloride

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CuCl2 is the chemical formula for Copper II chloride. Similarly, this salt has a molar mass of 134.45 g mol-1. This salt has a molecular mass of 170.48 g mol-1 in its dehydrated state. Furthermore, this anhydrous salt has one cation Cu2+ and two anion Clin its structure.

Structure of Copper Chloride
Structure of Copper Chloride

Copper (II) chloride has a deformed octahedron structure with 6 chloride anions coupled to a copper cation. In this dehydrated state, it takes the shape of a Cu2+-centred atom surrounded by two water molecules and two chlorine anions Cl.


Occurrence of Copper Chloride

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When it comes to Copper (II) chloride, these salts can be found in anhydrous or dehydrated form in the uncommon minerals tolbachite and eriochalcite. It's also found in abundance in fumaroles.


Preparation of Copper Chloride

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To make copper chloride, combine metallic copper with chlorine in the following way:

CuCl2 = Cu + Cl+ 2 H2O

Copper (II) chloride can also be made by mixing copper (II) hydroxide or copper (II) carbonate with hydrochloric acid:

CuCl2 + 2 H2O = Cu (OH) 2 + 2HCl


Physical Properties of Copper Chloride

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  • Copper (II) chloride is blue-green in colour and fairly solid in its dehydrated state. 
  • In anhydrous form it is similarly yellow-brown in colour and solid. 
  • Copper (II) chloride has a density of 3.38 g mL-1 in anhydrous form and 2.51 g mL-1 in dehydrate form.
  • The anhydrous salt has a melting point of 498 degrees Celsius. 
  • Similarly, the anhydrous salt decomposes at 993 oC. Water, methanol, ethanol, and acetone are all stated to be soluble in copper (II) chloride.

Chemical Properties of Copper Chloride

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  • Copper chloride is a very adaptable salt that can survive a wide range of reactions. As a result, it is suitable for use in the chemical industry or chemical synthesis. 
  • When a reductant is present, copper (II) chloride can undergo a redox reaction. Metallic copper or cuprous salt make up the produced compounds: 2 CuCl + 2 HCl + H2SO4 = 2 CuCl + 2 SO2 + 2 H2O
  • Copper (II) chloride can be replaced by copper (II) hydroxide in the presence of bases: Cu (OH)2 + 2 NaCl = CuCl2 + 2 NaOH

Uses of Copper Chloride

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  • Palladium (II) chloride may be made using copper (II) chloride as a catalyst in combination with other chloride salts. 
  • One of the most popular applications is the conversion of ethylene to acetaldehyde. CH3CHO + Pd + 2 HCl = C2H4 + PdCl2 + H2O
  • Copper (II) chloride is the most commonly used pyrotechnic chemical because of its blue/green colour.

Precautions of Copper Chloride

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  • Copper (II) chloride is extremely poisonous at high quantities. 
  • It can also react with oxidising substances in the same way. This substance is non-flammable.

Things To Remember

  • Cupric chloride is another name for copper (II) chloride. It is also an inorganic salt. In chemical synthesis, this salt is also used as a catalyst.
  • CuCl2 is the chemical formula for Copper II chloride. Similarly, this salt has a molar mass of 134.45 g mol-1. This salt has a molecular mass of 170.48 g mol-1 in its dehydrated state. 
  • When it comes to Copper (II) chloride, these salts can be found in anhydrous or dehydrated form in the uncommon minerals tolbachite and eriochalcite. 
  • Copper (II) chloride is blue-green in colour and fairly solid in its dehydrated state. In anhydrous form it is similarly yellow-brown in colour and solid.
  • Copper chloride is a very adaptable salt that can survive a wide range of reactions. As a result, it is suitable for use in the chemical industry or chemical synthesis.
  • Palladium (II) chloride may be made using copper (II) chloride as a catalyst in combination with other chloride salts.

Sample Questions

Ques: What will be the colour of copper (II) chloride in dehydrated form? (1 mark)

Ans: The colour of copper chloride in dehydrated form is blue-green.

Ques: Which chemical reaction is involved in Copper (II) Chloride? (2 marks)

Ans: Chemical reactions involved in the preparation of Copper Chloride is-

Cu + H2O2 → CuO + H2

CuO + 2HCl → CuCl2 + H2O

Ques: Name the minerals in which Copper (II) Chloride are found. (1 mark)

Ans: Copper(II) Chloride is found in Tolbachite and Eriochalcite.

Ques: What are the ions present in Copper Chloride? (2 marks)

Ans: Copper Chloride contains the metallic copper ion and chloride, the chlorine ion. The positive charge of the copper ion is two, whereas the negative charge of the chlorine ion is one. 

Ques: What is the molar mass of Copper Chloride? (1 mark)

Ans: Copper Chloride has a molar mass of 134.45 g mol-1

Ques: What is the molecular mass of Copper Chloride? (1 mark)

Ans: This salt has a molecular mass of 170.48 g mol-1 in its dehydrated state. 

Ques: What is the structure of the salt Copper Chloride? (1 mark)

Ans: The structure of Copper Chloride is shown below-

The structure of Copper Chloride
The structure of Copper Chloride

Ques: Write some precautions to take while handling Copper Chloride. (2 marks)

Ans: Some precautions while handling Copper Chloride are-

  • Cupric chloride can cause irritation to the skin and eyes, as well as eye damage.
  • Inhaling the substance irritates the nose, throat, and lungs, causing coughing.
  • CuCl2 can irritate your stomach, producing salivation, nausea, vomiting, stomach soreness, and diarrhoea after ingestion.

Ques: What is the other name for Copper (II) Chloride? (1 mark)

Ans: Copper Chloride is also known as Cupric Chloride.

Ques: What is the boiling and melting point of Copper Chloride? (1 mark)

Ans: Boiling point and melting point of Copper (II) Chloride are 993 degrees Celsius and 498 degrees Celsius respectively. 

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