
Education Journalist | Study Abroad Lead
Rubber is commonly associated with elastic bands, automotive tires, and pencil erasers. However, this super-stretchy material is used in thousands of items, including rubber stamps and waterproof shoes, as well as surfing wetsuits, swimming caps, and dishwashing hoses. Rubber, which has been used for over 1000 years, was formerly solely derived from natural sources; however, rubber goods are today just as likely to be manufactured artificially in chemical factories. This is primarily due to the fact that we cannot create enough natural rubber to fulfil all of our demands. That, in turn, is due to the incredible utility of rubber.
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Key takeaways: Elastic, elastomer, polymer, latex, vulcanization, tapping, polymer chain, synthetic rubber.
What is rubber?
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Rubber is an elastic made from the exudations (oozing out) of certain tropical plants or petroleum and natural gas. Rubber is the primary component of tires used in automobiles, aeroplanes, and bicycles because of its flexibility, durability, and hardness. More than half of all rubber produced is used in automotive tires, with the remainder going into mechanical parts like mountings, gaskets, belts, and hoses, as well as consumer goods like shoes, clothes, furniture, and toys. Elastomers, or "elastic polymers," are the major chemical ingredients of rubber. Elastomers are long chainlike molecules that can be stretched to vast distances and still return to their original shape.
Types of rubber
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Each type of rubber material, whether natural or synthetic, has unique qualities that make it suited for specific uses. The following are some of the most prevalent types of rubber based on their origin:
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Natural Rubber: A rubber that is naturally formed by plants is known as natural rubber. It is created from the sap of the rubber trees.
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Synthetic Rubber: It is an artificial or man-made rubber. The commonly found synthetic rubber includes isoprene rubber, butyl rubber, silicon rubber, etc.
Natural rubber
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Natural rubber is a polymer that is made from plants. A big molecule comprises numerous smaller molecules of the same kind. Some polymers are created in labs and factories, while others are found in nature. A polymer is a chemical substance composed of numerous tiny molecules of the same kind. Some polymers are created in labs and factories, while others are found in nature.
One of the most significant polymers for human society is natural rubber. Natural rubber is an important raw resource that is used to make over 40,000 different goods. It's found in medical gadgets, surgical gloves, plane and vehicle tires, pacifiers, clothing, and toys, among other things. Natural rubber is made from latex, which is a yellowish milky fluid made up of proteins, carbohydrates, alkaloids, and other substances generated by a variety of plants. It also contains rubber in some plants, which is a milky liquid found in latex vessels (ducts) or rubber-producing plant cells. Only 2,500 types of plants have been identified to contain rubber in their latex, despite the fact that around 20,000 species of plants generate latex.
Natural rubber has been utilized in engineering for many years for one simple reason: it can withstand a lot of pressure while still performing critical duties.
How is Natural Rubber Made?
Natural rubber is created from the sap of rubber trees as a starting ingredient. Rubber latex is collected by tapping the rubber plants.
- An incision is cut into the rubber tree's bark for this, and the latex sap is collected in cups.
- The raw natural rubber is refined once the latex sap is collected to make it useful rubber.
- Originally, acid was added to the latex, causing the sap to harden like jelly. The latex jelly was then flattened and rolled into rubber sheets, which were then hung to dry.
Charles Goodyear developed a more complex method of making rubber stronger and more elastic in 1839. This was the vulcanization of rubber.
Natural rubber that has not been processed is sticky, deforms readily when heated, and is brittle when cold. It cannot be utilized to manufacture items with a high amount of elasticity in this state. The polymer chains are vulcanized, which inhibits them from moving independently. As a result, when vulcanized rubber is stressed, it deforms, but when the tension is released, the product returns to its original shape.
Source of Natural Rubber
Hundreds of different plant species are used to make natural rubber. The most important source, however, is a tropical tree endemic to the tropical Americas called Hevea brasiliensis. This tree thrives in climates with an annual rainfall of less than 2000 mm and temperatures ranging from 21 to 28 degrees. The optimal growth region is roughly 10 degrees on each side of the equator due to these characteristics and the tree's preferred height of around 600 meters. It is, however, grown further north in China, Mexico, and Guatemala.
Properties of Natural Rubber
Some of the unique properties of natural rubber are as follows:
- Natural rubber combines strong tensile and tears strength with excellent fatigue resistance.
- It has great green strength and tack, which means it can attach to itself as well as other materials, making fabrication easier.
- One of its disadvantages is that it has a modest resistance to environmental degradation caused by heat, light, and ozone.
- Natural rubber adheres well to a brass-plated steel cable, making it perfect for use in rubber tires.
- It has a low hysteresis, which means it generates less heat, preserving new tire service integrity and extending retreadability.
- Natural rubber has a low rolling resistance and improves fuel efficiency.
- Cutting, chipping, and tearing resistance is excellent.
Uses of Natural Rubber
Some of the uses of natural rubber are as given below:
- Natural rubber is a good water repellent.
- This may be the most effective defence against infections like the AIDS virus (HIV). Latex is utilized in condoms, surgical and medical examination gloves for this reason.
- Natural rubber is a great material for springs.
- Catheters, balloons, medical tubes, elastic thread, and various adhesives all include natural rubber latex.
- It is the only raw material utilized by the car industry, other than rayon.
- Rubberwood is a byproduct of natural rubber that is becoming increasingly important. It serves as a supply of charcoal for the local community's cooking.
Things to remember
- Rubber is a natural product made by plants that may be found in many of the items we use on a daily basis.
- Natural rubber is an elastic material made from the latex sap of trees, particularly those belonging to the Hevea and Ficus species.
- More than half of all rubber produced is used in automotive tires, with the remainder going into mechanical parts like mountings, gaskets, belts, and hoses, as well as consumer goods like shoes, clothes, furniture, and toys.
- Rubber's properties include tremendous strength and the ability to stretch repeatedly without breaking.
- Natural rubber compositions are extremely flexible, have excellent electrical insulating properties, and are resistant to a wide range of corrosive chemicals.
Sample Questions
Ques: What is the process of rubber vulcanization? [5 marks]
Ans: Vulcanization is a chemical reaction that involves heating elastomeric materials with an agent (usually Sulphur), an activator, an accelerator, and occasionally a retarder to generate a cross-linked molecular network. Elasticity, resilience, tensile strength, viscosity, hardness, and weather resistance are all increased as a consequence. Any sort of rubber that has been hardened using heat and Sulphur is known as vulcanized rubber.
It involves three steps:
- Induction, flow time, or scorch
- Crosslinking or cure
- The optimum state of cure or over cure
Ques: What is natural rubber? [3 marks]
Ans: Natural rubber is an elastic material made from the latex sap of trees, particularly those belonging to the Hevea and Ficus species. Natural rubber is an elastomer, or an elastic hydrocarbon polymer, in technical terms. Natural rubber is one of the varieties of rubber, along with vulcanized rubber, which is used to make a range of rubber goods. India rubber, gum elastic, and caoutchouc are all names for natural rubber.
Ques: What are the advantages of natural rubber? [5 marks]
Ans: The advantages of natural rubber are:
- It's possible to compound it to fulfil almost any mechanical need.
- It has the ability to be totally conductive or electrically insulating
- It is protective, insulating, and has a sealing characteristic.
- Even in heavy-duty applications, the capacity to absorb vibration and shock while reducing noise is exceptional.
Ques: How is natural rubber produced? [5 marks]
Ans: The rubber is extracted in the form of latex, a white, milky fluid held in cells found in the inner layers of the tree's bark, using a technique known as 'tapping,' which entails paring away a thin slice of bark without damaging the growing layer in a series of half-spiral cuts, usually on alternate days, with a special knife. The latex then oozes out of the cut and pours into a collecting cup for many hours or longer, until it coagulates and the flow stops.
The latex, which is about 70% water at this time, may be brought to a processing factory and sieved to remove foreign materials, mixed, coagulated, rolled into sheets, and then dried in 'smokehouses' to make 'ribbed smoked sheets (RSS).
Alternatively, it can be cleaned, shredded, and granulated under controlled circumstances after coagulation before being dried in deep-bed driers to make Technically Specified Rubber, a 'block' rubber (TSR). The rubber is then compacted into bales and packaged in polythene bags for delivery, regardless of the method utilized. Finally, a tiny amount of natural rubber is processed and marketed as latex concentrate; water is removed by centrifugation, creaming, or evaporation to yield a product with roughly 60% rubber.
Ques: What are the uses of natural rubber? [5 marks]
Ans: Natural rubber is employed where a high level of wear and heat resistance is required. Its uses include:
- Natural rubber is utilized in technical applications such as anti-vibration mounts, drive couplings, springs, bearings, rubber bands, and adhesives because of its strength and compressibility.
- Because of its strength and heat resistance, natural rubber is utilized in high-performance tires for race vehicles, buses, and aeroplanes.
- It’s also used in hoses, automotive parts, foam mattresses, and battery boxes.
Ques: What are the properties of natural rubber? [5 marks]
Ans: The properties of natural rubber are:
- Natural rubber possesses impurities and is vulnerable to environmental conditions and hydrocarbons, as well as flexibility and strength.
- Natural rubber is one of the most flexible varieties, and its water and chemical resistant.
- With a working temperature range of -58 to 212 degrees F, it's also resistant to cutting, tearing, wear, fatigue, and abrasion.
- It has high tensile strength and clings to other materials with ease.
- Natural rubber adheres well to a brass-plated steel cable, making it perfect for use in rubber tires.
- It has a low hysteresis, which means it generates less heat, preserving new tire service integrity and extending retreadability.
- Natural rubber has a low rolling resistance and improves fuel efficiency.
Ques: List some of the applications of natural rubber. [5 marks]
Ans: Some of the applications of natural rubber are:
- Shock mounts
- Vibration isolators
- Gaskets
- Seals
- Rolls
- Hose and tubing
- Tires
- Bushings
- Pad assemblies
- Loading dock bumpers
Ques: What are the types of rubber? [5 marks]
Ans: Based on their origin rubbers are of two: types
- Natural rubber is manufactured from latex, a flowing, milky white substance that oozes out of certain plants when they are cut. (Common dandelions, for example, generate latex, which may be seen pouring from their stems when snapped off.)
- Synthetic rubber is manufactured at chemical facilities utilizing petrochemicals as a starting material. Neoprene (the brand name for polychloroprene) is one of the earliest (and remains one of the most well-known), which is created by reacting acetylene with hydrochloric acid. Another synthetic rubber often used in automobile tires is emulsion styrene-butadiene rubber (E-SBR).
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