CBSE Class 12 Chemistry Question Paper 2009 Outside Delhi Set 56 1

CBSE CLASS XII Questions

• 1.

  (a) Define 'Denatured Protein' with an example.

  (b) What happens when glucose reacts with HCN ? Write the reaction involved.

  (c) Name the disease caused by the deficiency of Vitamin C.

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• 2.

  Consider the decomposition of hydrogen peroxide \( (\mathrm{H_2O_2}) \) as per the equation given below : \[ 2\mathrm{H_2O_2} \xrightarrow[\text{Alkaline medium}]{I^-} 2\mathrm{H_2O} + \mathrm{O_2} \] The mechanism for this reaction was found to be : Step I : \( \mathrm{H_2O_2} + I^- \longrightarrow \mathrm{H_2O} + IO^- \) (slow) Step II : \( \mathrm{H_2O_2} + IO^- \longrightarrow \mathrm{H_2O} + I^- + \mathrm{O_2} \) (fast) (a) Write the rate law expression. (b) Determine the order of reaction with respect to \( \mathrm{H_2O_2} \), \( I^- \) and overall order of reaction. (c) What is the molecularity of the reaction in Step II ?

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• 3.

  Draw the structures of major monohalo products in each of the following :

  (a)

  (b)

  
  

  

  
  

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• 4.

  An organic compound (X) has the molecular formula \(C_5H_{10}O\). Draw structures for (X) if it:
  (I) does not give Tollen's test but gives a positive iodoform test.
  (II) does not give Tollen's test and iodoform test but undergoes Aldol condensation.
  (III) undergoes Cannizzaro's reaction.
  

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• 5.

  Conductivity of \( 2.5 \times 10^{-4} \) M methanoic acid solution is \( 5.25 \times 10^{-5} \) S cm\(^{-1}\).

  (a) Calculate its molar conductivity.

  (b) Calculate its degree of dissociation.

  [Given : \( \lambda^{\circ}_{(\mathrm{H^+})} = 349.5 \) S cm\(^2\) mol\(^{-1}\) and \( \lambda^{\circ}_{(\mathrm{HCOO^-})} = 50.5 \) S cm\(^2\) mol\(^{-1}\)]

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• 6.

  A reaction \( \mathrm{A \rightarrow B} \) follows second order kinetics. How will the rate of reaction be affected if the concentration of (i) A is increased by three times, and (ii) A is reduced to half ?

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