What is the relation between kp and kc for a gaseous reaction, 2B -> A?

CBSE CLASS XII Related Questions

  • 1.
    Consider the decomposition of hydrogen peroxide \( (\mathrm{H_2O_2}) \) as per the equation given below : \[ 2\mathrm{H_2O_2} \xrightarrow[\text{Alkaline medium}]{I^-} 2\mathrm{H_2O} + \mathrm{O_2} \] The mechanism for this reaction was found to be : Step I : \( \mathrm{H_2O_2} + I^- \longrightarrow \mathrm{H_2O} + IO^- \) (slow) Step II : \( \mathrm{H_2O_2} + IO^- \longrightarrow \mathrm{H_2O} + I^- + \mathrm{O_2} \) (fast) (a) Write the rate law expression. (b) Determine the order of reaction with respect to \( \mathrm{H_2O_2} \), \( I^- \) and overall order of reaction. (c) What is the molecularity of the reaction in Step II ?


      • 2.

        Conductivity of \( 2.5 \times 10^{-4} \) M methanoic acid solution is \( 5.25 \times 10^{-5} \) S cm\(^{-1}\).

        (a) Calculate its molar conductivity.

        (b) Calculate its degree of dissociation.

        [Given : \( \lambda^{\circ}_{(\mathrm{H^+})} = 349.5 \) S cm\(^2\) mol\(^{-1}\) and \( \lambda^{\circ}_{(\mathrm{HCOO^-})} = 50.5 \) S cm\(^2\) mol\(^{-1}\)]


          • 3.
            Which of the following curve represents the first order reaction?

              • A
              • B
              • C
              • D

            • 4.

              (a) Write two structural differences between DNA and RNA.

              (b) Which component of starch is a branched chain polymer of \( \alpha \)-D-(+)-glucose ? Write its one characteristic feature.

              (c) Which types of bonds hold the polypeptide chains in fibrous proteins ?


                • 5.

                  (i) Why do Zr and Hf exhibit similar properties ?

                  (ii) "\( E^\circ \) for \( \mathrm{Mn^{3+}/Mn^{2+}} \) couple is more positive than that for \( \mathrm{Fe^{3+}/Fe^{2+}} \)." Justify the statement.

                  [Atomic number : Mn = 25, Fe = 26]


                    • 6.
                      The chelating ligand used for the treatment of lead poisoning is :

                        • Ethane-1,2-diamine
                        • Oxalate ion
                        • Dimethylglyoxime
                        • EDTA
                      CBSE CLASS XII Previous Year Papers

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