NCERT Solutions For Class 12 Chemistry Chapter 12: Aldehydes, Ketones and Carboxylic Acids

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Jasmine Grover

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NCERT Solutions for Class 12 Chemistry Chapter 12 Aldehydes Ketones and Carboxylic Acids deals with Aldehydes, Ketones and Carboxylic Acid that are organic compounds containing Carbonyl group (CO) as the functional group. The important topics of  Aldehydes Ketones and Carboxylic Acids chapter include:

  1. Physical Properties
  2. Uses of Carboxylic Acids
  3. Aldehyde
  4. Cannizzaro Reaction
  5. Etard Reaction
  6. Nucleophilic Addition Reaction
  7. Tollen’s Test
  8. Fehling’s Test
  9. Carbonyl Compounds
  10. Clemmensen Reduction Reaction
  11. Addition Reaction

Expected no. of questions: 3 to 6 questions of total 8 marks

Download PDF: NCERT Solutions for Class 12 Chemistry Chapter 12 pdf


NCERT Solutions for Class 12 Chemistry Chapter 12

NCERT Solutions for Class 12 Chemistry Chapter 12 is given below. 

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Class 12 Chemistry Aldehydes, Ketones & Carboxylic Acid – Important Topics

Carbonyl compounds are those compounds that contain a carbon-oxygen double bond in them. Aldehydes, Ketones and Carboxylic acids are carbonyl compounds as they have C=O group in them.

  • The carbon atom of the carbonyl compound is an sp²-hybridized atom. It forms 3 sigma bonds. 
  • The fourth valence electron remains in the p-orbital.
  • Carbonyl compounds forms a Pi bond with the oxygen by overlapping with the p-orbital of the oxygen atom. 
  • The bond angle of the carbonyl compound is around 120 degrees.
  • The carboxyl carbon bonds of the carboxylic acid lie on one plane. 
  • The carboxylic carbon has less electrophilic property than the carbonyl compound due to resonating structures.

Properties of Aldehydes & Ketones

  • Aldehydes and Ketones have higher boiling points.
  • Methanal is gaseous at room temperature while ethanal is a volatile liquid.
  • The solubility of Aldehydes and ketones compounds increases as the length of the alkyl chain increases.
  • Aldehydes and ketones undergo nucleophilic reactions. 
  • Aldehydes are more reactive as compared to ketones.
  • Aldehydes are also used for mirror silvering.
  • Acetone is used as an industrial solvent.

Properties of Carboxylic Acid:

  • Higher carboxylic acids are waxy solids whereas lower aliphatic carboxylic acids are liquid in nature.
  • Carboxylic acids mostly have higher boiling points than aldehydes and ketones.
  • Solubility decreases with an increase in the number of carbon atoms.
  • Carboxylic acids also undergo esterification reactions when they are reacted with alcohols or phenol in the presence of a catalyst.
  • Carboxylic acids are used as food preservatives.

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CBSE CLASS XII Related Questions

  • 1.
    Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane.


      • 2.
        Give structures of A, B and C: Aniline $\xrightarrow{Br_2/H_2O}$ A $\xrightarrow{NaNO_2+HCl, 0-5^\circ C}$ B $\xrightarrow{H_3PO_2+H_2O}$ C


          • 3.
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              • 4.
                Which isomer of $C_4H_9Br$ is most reactive towards $S_N1$ reaction?


                  • 5.
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                      • 6.
                        For decomposition of $H_2O_2$ by $I^-$: Step I: $H_2O_2 + I^- \rightarrow H_2O + IO^-$ (slow). Step II: $H_2O_2 + IO^- \rightarrow H_2O + I^- + O_2$ (fast). (a) Write rate law. (b) Determine order w.r.t. $H_2O_2$ and $I^-$ and overall order. (c) Molecularity of Step II.

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