JEE Main 2013 April 23 Question Paper is available here with solutions PDF and detailed solutions for every question. CBSE conducted the online (CBT) JEE Main 2013 Paper 1 (B.E./B.Tech) on April 23, 2013. The question paper includes the following:

  • 90 questions in a 3-hour CBT Mode: 30 each from Mathematics, Physics and Chemistry
  • Question type: multiple choice questions (MCQs) with 4 options, one correct answer
  • Marking: +4 for a correct answer, -1 for an incorrect answer, 0 for an unattempted question
  • Maximum marks: 360 (120 per subject)

JEE Main 2013 April 23 Question Paper with Solution PDF

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JEE Main 2013 April 23 Questions with Solutions


Mathematics (Q1 - Q30)

Question 1:

The least integral value \(\alpha\) of \(x\) such that \(\dfrac{x-5}{x^2+5x-14} \gt 0\), satisfies :

  • (A) \(\alpha^2 + 3\alpha - 4 = 0\)
  • (B) \(\alpha^2 - 5\alpha + 4 = 0\)
  • (C) \(\alpha^2 - 7\alpha + 6 = 0\)
  • (D) \(\alpha^2 + 5\alpha - 6 = 0\)

Question 2:

Let \( a=Im\left(\frac{1+z^{2}}{2iz}\right), \) where \( z \) is any non-zero complex number. The set \( A=\left\{a:\left|z\right|=1\,and\,z\ne\pm1\right\} \) is equal to:

  • (A) \( ( - 1, 1) \)
  • (B) \( [ - 1, 1] \)
  • (C) \( [0, 1) \)
  • (D) \( ( - 1, 0] \)

Question 3:

The sum of the series : \((2)^2 + 2(4)^2 + 3(6)^2 + \ldots\) upto 10 terms is :

  • (A) 11300
  • (B) 11200
  • (C) 12100
  • (D) 12300

Question 4:

If \(a_1, a_2, a_3, \ldots, a_n, \ldots\) are in A.P. such that \(a_4 - a_7 + a_{10} = m\), then the sum of first 13 terms of this A.P., is :

  • (A) \(10\,m\)
  • (B) \(12\,m\)
  • (C) \(13\,m\)
  • (D) \(15\,m\)

Question 5:

The sum of the rational terms in the binomial expansion of \(\left(2^{\frac{1}{2}} + 3^{\frac{1}{5}}\right)^{10}\) is :

  • (A) 25
  • (B) 32
  • (C) 9
  • (D) 41

Question 6:

The number of solutions of the equation \(\sin 2x - 2\cos x + 4\sin x = 4\) in the interval \([0, 5\pi]\) is :

  • (A) 3
  • (B) 5
  • (C) 4
  • (D) 6

Question 7:

If two lines \(L_1\) and \(L_2\) in space, are defined by
\(L_1 = \{x = \sqrt{\lambda}\,y + (\sqrt{\lambda} - 1),\ z = (\sqrt{\lambda} - 1)\,y + \sqrt{\lambda}\}\) and
\(L_2 = \{x = \sqrt{\mu}\,y + (1 - \sqrt{\mu}),\ z = (1 - \sqrt{\mu})\,y + \sqrt{\mu}\}\)
then \(L_1\) is perpendicular to \(L_2\), for all nonnegative reals \(\lambda\) and \(\mu\), such that :

  • (A) \(\sqrt{\lambda} + \sqrt{\mu} = 1\)
  • (B) \(\lambda \ne \mu\)
  • (C) \(\lambda + \mu = 0\)
  • (D) \(\lambda = \mu\)

Question 8:

Let \(\theta_1\) be the angle between two lines \(2x + 3y + c_1 = 0\) and \(-x + 5y + c_2 = 0\) and \(\theta_2\) be the angle between two lines \(2x + 3y + c_1 = 0\) and \(-x + 5y + c_3 = 0\), where \(c_1, c_2, c_3\) are any real numbers :
Statement-1 : If \(c_2\) and \(c_3\) are proportional, then \(\theta_1 = \theta_2\).
Statement-2 : \(\theta_1 = \theta_2\) for all \(c_2\) and \(c_3\).

  • (A) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation of Statement-1.
  • (B) Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation of Statement-1.
  • (C) Statement-1 is false; Statement-2 is true.
  • (D) Statement-1 is true; Statement-2 is false.

Question 9:

If the circle \(x^2 + y^2 - 6x - 8y + (25 - a^2) = 0\) touches the axis of \(x\), then \(a\) equals.

  • (A) 0
  • (B) \(\pm 4\)
  • (C) \(\pm 2\)
  • (D) \(\pm 3\)

Question 10:

The point of intersection of the normals to the parabola \(y^2 = 4x\) at the ends of its latus rectum is :

  • (A) \((0, 2)\)
  • (B) \((3, 0)\)
  • (C) \((0, 3)\)
  • (D) \((2, 0)\)

Question 11:

A tangent to the hyperbola \( \frac{x^{4}}{4}-\frac{y^{2}}{2}=1 \) meets x-axis at \( P \) and y-axis at \( Q \). Lines \( PR \) and \( QR \) are drawn such that \( OPRQ \) is a rectangle (where \( O \) is the origin). Then \( R \) lies on :

  • (A) \( \frac{4}{x^{2}}+\frac{2}{y^{2}}=1 \)
  • (B) \( \frac{2}{x^{2}}-\frac{4}{y^{2}}=1 \)
  • (C) \( \frac{2}{x^{2}}+\frac{4}{y^{2}}=1 \)
  • (D) \( \frac{4}{x^{2}}-\frac{2}{y^{2}}=1 \)

Question 12:

For integers \(m\) and \(n\), both greater than 1, consider the following three statements : \(P : m\) divides \(n\) \(Q : m\) divides \(n^2\) \(R : m\) is prime, then

  • (A) \(Q \wedge R \rightarrow P\)
  • (B) \(P \wedge Q \rightarrow R\)
  • (C) \(Q \rightarrow R\)
  • (D) \(Q \rightarrow P\)

Question 13:

If the median and the range of four numbers \(\{x, y, 2x+y, x-y\}\), where \(0 \lt y \lt x \lt 2y\), are 10 and 28 respectively, then the mean of the numbers is :

  • (A) 18
  • (B) 10
  • (C) 5
  • (D) 14

Question 14:

If the extremities of the base of an isosceles triangle are the points \( (2a, 0) \) and \( (0, a) \) and the equation of one of the sides is \( x = 2a \), then the area of the triangle, in square units, is :

  • (A) \( \frac{5}{4}a^{2} \)
  • (B) \( \frac{5}{2}a^{2} \)
  • (C) \( \frac{25a^2}{4} \)
  • (D) \( 5a^2 \)

Question 15:

On the sides \( AB, BC, CA \) of a \( \Delta ABC, 3, 4, 5 \) distinct points (excluding vertices \( A, B, C \)) are respectively chosen. The number of triangles that can be constructed using these chosen points as vertices a re :

  • (A) \( 210 \)
  • (B) \( 205 \)
  • (C) \( 215 \)
  • (D) \( 220 \)

Question 16:

Let \(R=\{(x, y) : x, y \in N \text{ and } x^2-4xy+3y^2=0\}\), where \(N\) is the set of all natural numbers. Then the relation \(R\) is :

  • (A) reflexive but neither symmetric nor transitive.
  • (B) symmetric and transitive.
  • (C) reflexive and symmetric,
  • (D) reflexive and transitive.

Question 17:

Let A, other than I or \(-I\), be a \(2 \times 2\) real matrix such that \(A^2=I\), I being the unit matrix. Let \(\mathrm{Tr}(A)\) be the sum of diagonal elements of A.
Statement-1: \(\mathrm{Tr}(A)=0\)
Statement-2: \(\det(A)=-1\)

  • (A) Statement-1 is true; Statement-2 is false.
  • (B) Statement-1 is true; Statement-2 is true; Statement-2 is not a correct explanation for Statement-1.
  • (C) Statement-1 is true; Statement-2 is true; Statement-2 is a correct explanation for Statement-1.
  • (D) Statement-1 is false; Statement-2 is true.

Question 18:

Statement-1: The system of linear equations
\(x+(\sin\alpha)y+(\cos\alpha)z=0\)
\(x+(\cos\alpha)y+(\sin\alpha)z=0\)
\(x-(\sin\alpha)y-(\cos\alpha)z=0\)
has a non-trivial solution for only one value of \(\alpha\) lying in the interval \(\left(0, \frac{\pi}{2}\right)\).
Statement-2: The equation in \(\alpha\)
\(\begin{vmatrix}\cos\alpha & \sin\alpha & \cos\alpha\\ \sin\alpha & \cos\alpha & \sin\alpha\\ \cos\alpha & -\sin\alpha & -\cos\alpha\end{vmatrix}=0\)
has only one solution lying in the interval \(\left(0, \frac{\pi}{2}\right)\)

  • (A) Statement-1 is true, Statement-2 is true, Statement-2 is not correct explanation for Statement-1.
  • (B) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for Statement-1.
  • (C) Statement-1 is true, Statement-2 is false.
  • (D) Statement-1 is false, Statement-2 is true.

Question 19:

\(S=\tan^{-1}\left(\frac{1}{n^2+n+1}\right)+\tan^{-1}\left(\frac{1}{n^2+3n+3}\right)+\ldots+\tan^{-1}\left(\frac{1}{1+(n+19)(n+20)}\right)\), then \(\tan S\) is equal to :

  • (A) \(\frac{20}{401+20n}\)
  • (B) \(\frac{n}{n^2+20n+1}\)
  • (C) \(\frac{20}{n^2+20n+1}\)
  • (D) \(\frac{n}{401+20n}\)

Question 20:

Let \(f\) be a composite function of \(x\) defined by \(f(u)=\frac{1}{u^2+u-2},\ u(x)=\frac{1}{x-1}\). Then the number of points \(x\) where \(f\) is discontinuous is :

  • (A) 4
  • (B) 3
  • (C) 2
  • (D) 1

Question 21:

If \( f(x) = sin\, (sin\, x) \) and \( f'' (x) + tan \,x\,f'(x)+ g(x) = 0, \) then \( g(x) \) is :

  • (A) \( cos^2\, x\, cos\, (sin\, x) \)
  • (B) \( sin^2\, x\, cos\, (cos\, x) \)
  • (C) \( sin^2\, x\, sin\, (cos\, x) \)
  • (D) \( cos^2\, x\, sin\, (sin\, x) \)

Question 22:

If the curves \(\frac{x^2}{\alpha}+\frac{y^2}{4}=1\) and \(y^3=16x\) intersect at right angles, then a value of \(\alpha\) is :

  • (A) 2
  • (B) \(\frac{4}{3}\)
  • (C) \(\frac{1}{2}\)
  • (D) \(\frac{3}{4}\)

Question 23:

The cost of running a bus from \( A \) to \( B \) , is \( Rs.\left(av+\frac{b}{v}\right) \) where \( v \) km/h is the average speed of the bus. When the bus travels at \( 30\, km/h \), the cost comes out to be \( Rs.\, 75 \) while at \( 40\, km/h \), it is \( Rs. \,65 \). Then the most economical speed (in \( km/ h \)) of the bus is :

  • (A) \( 45 \)
  • (B) \( 50 \)
  • (C) \( 60 \)
  • (D) \( 40 \)

Question 24:

If a curve passes through the point \(\left(2, \frac{7}{2}\right)\) and has slope \(\left(1-\frac{1}{x^2}\right)\) at any point \((x, y)\) on it, then the ordinate of the point on the curve whose abscissa is \(-2\) is :

  • (A) \(-\frac{3}{2}\)
  • (B) \(\frac{3}{2}\)
  • (C) \(\frac{5}{2}\)
  • (D) \(-\frac{5}{2}\)

Question 25:

The integral \( \int \frac{xdx}{2-x^{2}+\sqrt{2-x^{2}}} \) equals

  • (A) \( log\left|1+\sqrt{2+x^{2}}\right|+c \)
  • (B) \( -log\left|1+\sqrt{2-x^{2}}\right|+c \)
  • (C) \( -x\,log\left|1-\sqrt{2-x^{2}}\right|+c \)
  • (D) \( x\,log\left|1-\sqrt{2+x^{2}}\right|+c \)

Question 26:

The value of \(\displaystyle\int_{-\pi/2}^{\pi/2}\dfrac{\sin^2 x}{1+2^x}\,dx\) is :

  • (A) \(\pi\)
  • (B) \(\frac{\pi}{2}\)
  • (C) \(4\pi\)
  • (D) \(\frac{\pi}{4}\)

Question 27:

The area under the curve \(y=|\cos x-\sin x|,\ 0\le x\le\frac{\pi}{2}\), and above \(x\)-axis is :

  • (A) \(2\sqrt{2}\)
  • (B) \(2\sqrt{2}-2\)
  • (C) \(2\sqrt{2}+2\)
  • (D) 0

Question 28:

If \( \vec{a} \) and \( \vec{b} \) are non-collinear vectors, then the value of a for which the vectors \( \vec{u}=\left(\alpha-2\right)\vec{a}+\vec{b} \) and \( \vec{v}=\left(2+3\alpha\right)\vec{a}-3\vec{b} \) are collinear is :

  • (A) \( \frac{3}{2} \)
  • (B) \( \frac{2}{3} \)
  • (C) \( -\frac{3}{2} \)
  • (D) \( -\frac{2}{3} \)

Question 29:

If the projections of a line segment on the \(x\), \(y\) and \(z\)-axes in 3-dimensional space are 2, 3 and 6 respectively, then the length of the line segment is :

  • (A) 12
  • (B) 7
  • (C) 9
  • (D) 6

Question 30:

A, B, C try to hit a target simultaneously but independently. Their respective probabilities of hitting the targets are \(\frac{3}{4},\frac{1}{2},\frac{5}{8}\). The probability that the target is hit by A or B but not by C is :

  • (A) 21/64
  • (B) 7/8
  • (C) 7/32
  • (D) 9/64

Physics (Q31 - Q60)

Question 31:

If the time period \( t \) of the oscillation of a drop of liquid of density \( d \), radius \( r \), vibrating under surface tension \( s \) is given by the formula \( t=\sqrt{r^{2b}s^{c}d^{a/2}}. \) It is observed that the time period is directly proportional to \( \sqrt{\frac{d}{s}}. \) The value of \( b \) should therefore be :

  • (A) \( \frac{3}{4} \)
  • (B) \( \sqrt{3} \)
  • (C) \( \frac{3}{2} \)
  • (D) \( \frac{2}{3} \)

Question 32:

A 70 kg man leaps vertically into the air from a crouching position. To take the leap the man pushes the ground with a constant force \(F\) to raise himself. The center of gravity rises by 0.5 m before he leaps. After the leap the c.g. rises by another 1 m. The maximum power delivered by the muscles is : (Take \(g=10\ \mathrm{ms^{-2}}\))

  • (A) \(6.26\times10^{3}\) Watts at the start
  • (B) \(6.26\times10^{3}\) Watts at take off
  • (C) \(6.26\times10^{4}\) Watts at the start
  • (D) \(6.26\times10^{4}\) Watts at take off

Question 33:

A boy of mass 20 kg is standing on a 80 kg free to move long cart. There is negligible friction between cart and ground. Initially, the boy is standing 25 m from a wall. If he walks 10 m on the cart towards the wall, then the final distance of the boy from the wall will be

  • (A) 15 m
  • (B) 12.5 m
  • (C) 15.5 m
  • (D) 17 m

Question 34:

A projectile of mass \( M \) is fired so that the horizontal range is \( 4\, km \). At the highest point the projectile explodes in two parts of masses \( M/4 \) and \( 3M/4 \) respectively and the heavier part starts falling down vertically with zero initial speed. The horizontal range (distance from point of firing) of the lighter part is :

  • (A) 16 km
  • (B) 1 km
  • (C) 10 km
  • (D) 2 km

Question 35:

A particle of mass 2 kg is moving such that at time \(t\), its position, in meter, is given by \(\vec{r}(t)=5\hat{i}-2t^2\hat{j}\). The angular momentum of the particle at \(t=2\,\mathrm{s}\) about the origin in \(\mathrm{kgm^{-2}\,s^{-1}}\) is :

  • (A) \(-80\hat{k}\)
  • (B) \((10\hat{i}-16\hat{j})\)
  • (C) \(-40\hat{k}\)
  • (D) \(40\hat{k}\)

Question 36:

A body of mass ' \(m\) ' is tied to one end of a spring and whirled round in a horizontal plane with a constant angular velocity. The elongation in the spring is 1 cm. If the angular velocity is doubled, the elongation in the spring is 5 cm. The original length of the spring is :

  • (A) 15 cm
  • (B) 12 cm
  • (C) 16 cm
  • (D) 10 cm

Question 37:

A copper wire of length 1.0 m and a steel wire of length 0.5 m having equal cross-sectional areas are joined end to end. The composite wire is stretched by a certain load which stretches the copper wire by 1 mm. If the Young's modulii of copper and steel are respectively \(1.0\times10^{11}\ \mathrm{Nm^{-2}}\) and \(2.0\times10^{11}\ \mathrm{Nm^{-2}}\), the total extension of the composite wire is :

  • (A) 1.75 mm
  • (B) 2.0 mm
  • (C) 1.50 mm
  • (D) 1.25 mm

Question 38:

Wax is coated on the inner wall of a capillary tube and the tube is then dipped in water. Then, compared to the unwaxed capillary, the angle of contact \(\theta\) and the height \(h\) upto which water rises change. These changes are :

  • (A) \(\theta\) increases and \(h\) also increases
  • (B) \(\theta\) decreases and \(h\) also decreases
  • (C) \(\theta\) increases and \(h\) decreases
  • (D) \(\theta\) decreases and \(h\) increases

Question 39:

A thin tube sealed at both ends is 100 cm long. It lies horizontally, the middle 20 cm containing mercury and two equal ends containing air at standard atmospheric pressure. If the tube is now turned to a vertical position, by what amount will the mercury be displaced ?
(Given : cross-section of the tube can be assumed to be uniform)

  • (A) 2.95 cm
  • (B) 5.18 cm
  • (C) 8.65 cm
  • (D) 0.0 cm

Question 40:

The ratio of the coefficient of volume expansion of a glass container to that of a viscous liquid kept inside the container is 1 : 4. What fraction of the inner volume of the container should the liquid occupy so that the volume of the remaining vacant space will be same at all temperatures ?

  • (A) 2 : 5
  • (B) 1 : 4
  • (C) 1 : 64
  • (D) 1 : 8

Question 41:

\(500 \,g\) of water and \(100\, g\) of ice at \(0^{\circ}C\) are in a calorimeter whose water equivalent is \(40\, g\). \(10\, g\) of steam at \(100^\circ C\) is added to it. Then water in the calorimeter is : (Latent heat of ice \(= 80\, cal/g\), Latent heat of steam \(=540\, cal/g\))

  • (A) \( 580\,g \)
  • (B) \( 590\,g \)
  • (C) \( 600\,g \)
  • (D) \( 610\,g \)

Question 42:

This question has Statement-1 and Statement-2. Of the four choices given after the Statements, choose the one that best describes the two Statements.
Statement 1: The internal energy of a perfect gas is entirely kinetic and depends only on absolute temperature of the gas and not on its pressure or volume.
Statement 2: A perfect gas is heated keeping pressure constant and later at constant volume. For the same amount of heat the temperature of the gas at constant pressure is lower than that at constant volume.

  • (A) Statement-1 is true, Statement-2 is true and Statement −2 is the correct explanation of Statement-1.
  • (B) Statement-1 is true, Statement-2 is false.
  • (C) Statement-1 is true, Statement-2 is true but Statement-2 is not the correct explanation of Statement-1.
  • (D) Statement-1 is false, Statement-2 is true.

Question 43:

Bob of a simple pendulum of length \(l\) is made of iron. The pendulum is oscillating over a horizontal coil carrying direct current. If the time period of the pendulum is T then :

  • (A) \(T \lt 2\pi\sqrt{\frac{l}{g}}\) and damping is smaller than in air alone.
  • (B) \(T = 2\pi\sqrt{\frac{l}{g}}\) and damping is larger than in air alone.
  • (C) \(T \gt 2\pi\sqrt{\frac{l}{g}}\) and damping is smaller than in air alone.
  • (D) \(T \lt 2\pi\sqrt{\frac{l}{g}}\) and damping is larger than in air alone.

Question 44:

A sonometer wire of length \( 114\, cm \) is fixed at both the ends. Where should the two bridges be placed so as to divide the wire into three segments whose fundamental frequencies are in the ratio \( 1 : 3 : 4 \) ?

  • (A) At 36 cm and 84 cm from one end
  • (B) At 24 cm and 72 cm from one end
  • (C) At 48 cm and 96 cm from one end
  • (D) At 72 cm and 96 cm from one end

Question 45:

Consider a finite insulated, uncharged conductor placed near a finite positively charged conductor. The uncharged body must have a potential :

  • (A) less than the charged conductor and more than at infinity.
  • (B) more than the charged conductor and less than at infinity.
  • (C) more than the charged conductor and more than at infinity.
  • (D) less than the charged conductor and less than at infinity.

Question 46:

A liquid drop having 6 excess electrons is kept stationary under a uniform electric field of 25.5 kVm\(^{-1}\). The density of liquid is \(1.26\times10^{3}\) kg m\(^{-3}\). The radius of the drop is (neglect buoyancy).

  • (A) \(4.3\times10^{-7}\) m
  • (B) \(7.8\times10^{-7}\) m
  • (C) \(0.078\times10^{-7}\) m
  • (D) \(3.4\times10^{-7}\) m

Question 47:

A parallel plate capacitor of area \( 60\, cm^2 \) and separation \( 3\, mm \) is charged initially to \( 90\, \mu C \). If the medium between the plate gets slightly conducting and the plate loses the charge initially at the rate of \( 2.5 \times 10^{-8}\, C/s \), then what is the magnetic field between the plates ?

  • (A) \( 2.5 \times 10^{-8}\, T \)
  • (B) \( 2.0 \times 10^{-7}\, T \)
  • (C) \( 1.63 \times 10^{-11}\, T \)
  • (D) zero

Question 48:

Which of the four resistances \(P, Q, R\) and \(S\) generate the greatest amount of heat when a current flows from A to B ?

  • (A) Q
  • (B) S
  • (C) P
  • (D) R

Question 49:

A rectangular loop of wire, supporting a mass \(m\), hangs with one end in a uniform magnetic field \(\vec{B}\) pointing out of the plane of the paper. A clockwise current is set up such that \(i \gt mg/Ba\), where \(a\) is the width of the loop. Then :

  • (A) The weight rises due to a vertical force caused by the magnetic field and work is done on the system.
  • (B) The weight do not rise due to vertical for caused by the magnetic field and work is done on the system.
  • (C) The weight rises due to a vertical force caused by the magnetic field but no work is done on the system.
  • (D) The weight rises due to a vertical force caused by the magnetic field and work is extracted from the magnetic field.

Question 50:

A particle of charge \(16\times10^{-16}\) C moving with velocity 10 ms\(^{-1}\) along \(x\)-axis enters a region where magnetic field of induction \(\vec{B}\) is along the \(y\)-axis and an electric field of magnitude \(10^{4}\) Vm\(^{-1}\) is along the negative \(z\)-axis. If the charged particle continues moving along \(x\)-axis, the magnitude of \(\vec{B}\) is :

  • (A) \(16\times10^{3}\) Wb m\(^{-2}\)
  • (B) \(2\times10^{3}\) Wb m\(^{-2}\)
  • (C) \(1\times10^{3}\) Wb m\(^{-2}\)
  • (D) \(4\times10^{3}\) Wb m\(^{-2}\)

Question 51:

The plot given below is of the average power delivered to an LRC circuit versus frequency. The quality factor of the circuit is :

  • (A) 5.0
  • (B) 2.0
  • (C) 2.5
  • (D) 0.4

Question 52:

Select the correct statement from the following

  • (A) Electromagnetic waves cannot travel in vacuum
  • (B) Electromagnetic waves are longitudinal waves
  • (C) Electromagnetic waves are produced by charges moving with uniform velocity
  • (D) Electromagnetic waves carry both energy and momentum as they propagate through space

Question 53:

This question has Statement-1 and Statement-2. Of the four choices given after the Statements, choose the one that best describes the two Statements.
Statement 1: Very large size telescopes are reflecting telescopes instead of refracting telescopes.
Statement 2: It is easier to provide mechanical support to large size mirrors than large size lenses.

  • (A) Statement-1 is true and Statement-2 is false.
  • (B) Statement-1 is false and Statement-2 is true.
  • (C) Statement-1 and statement-2 are true and Statement-2 is correct explanation for statement-1.
  • (D) Statements-1 and statement-2 are true and Statement-2 is not the correct explanation for statement-1.

Question 54:

A light ray falls on a square glass slab as shown in the diagram. The index of refraction of the glass, if total internal reflection is to occur at the vertical face, is equal to :

  • (A) \( \frac{\left(\sqrt{2}+1\right)}{2} \)
  • (B) \( \sqrt{\frac{5}{2}} \)
  • (C) \( \frac{3}{2} \)
  • (D) \( \sqrt{\frac{3}{2}} \)

Question 55:

\(n\) identical waves each of intensity \(I_0\) interfere with each other. The ratio of maximum intensities if the interference is (i) coherent and (ii) incoherent is :

  • (A) \(n^2\)
  • (B) \(\frac{1}{n}\)
  • (C) \(\frac{1}{n^2}\)
  • (D) \(n\)

Question 56:

Electrons are accelerated through a potential difference V and protons are accelerated through a potential difference 4 V. The de-Broglie wavelengths are \(\lambda_e\) and \(\lambda_p\) for electrons and protons respectively. The ratio of \(\frac{\lambda_e}{\lambda_p}\) is given by: (given \(m_e\) is mass of electron and \(m_p\) is mass of proton).

  • (A) \(\frac{\lambda_e}{\lambda_p}=\sqrt{\frac{m_p}{m_e}}\)
  • (B) \(\frac{\lambda_e}{\lambda_p}=\sqrt{\frac{m_e}{m_p}}\)
  • (C) \(\frac{\lambda_e}{\lambda_p}=\frac{1}{2}\sqrt{\frac{m_e}{m_p}}\)
  • (D) \(\frac{\lambda_e}{\lambda_p}=2\sqrt{\frac{m_p}{m_e}}\)

Question 57:

In the Bohr's model of hydrogen-like atom the force between the nucleus and the electron is modified as \(F=\dfrac{e^2}{4\pi\varepsilon_0}\left(\dfrac{1}{r^2}+\dfrac{\beta}{r^3}\right)\), where \(\beta\) is a constant. For this atom, the radius of the \(n^{th}\) orbit in terms of the Bohr radius \(\left(a_0=\dfrac{\varepsilon_0h^2}{m\pi e^2}\right)\) is :

  • (A) \(r_n=a_0n-\beta\)
  • (B) \(r_n=a_0n^2+\beta\)
  • (C) \(r_n=a_0n^2-\beta\)
  • (D) \(r_n=a_0n+\beta\)

Question 58:

A system of four gates is set up as shown. The 'truth table' corresponding to this system is :

  • (A)
  • (B)
  • (C)
  • (D)

Question 59:

Which of the following statement is NOT correct?

  • (A) Ground wave signals are more stable than the sky wave signals.
  • (B) The critical frequency of an ionospheric layer is the highest frequency that will be reflected back by the layer when it is vertically incident.
  • (C) Electromagnetic waves of frequencies higher than about 30MHz cannot penetrate the ionosphere.
  • (D) Sky wave signals in the broadcast frequency range are stronger at night than in the day time.

Question 60:

Correct set up to verify Ohm?s law is :

  • (A)
  • (B)
  • (C)
  • (D)

Chemistry (Q61 - Q90)

Question 61:

Number of atoms in the following samples of substances is largest in :

  • (A) \( 4.0\, g \) of hydrogen
  • (B) \( 71.0\, g \) of chlorine
  • (C) \( 127.0\,g \) of iodine
  • (D) \( 48.0\, g \) of magnesium

Question 62:

The de Broglie wavelength of a car of mass 1000 kg and velocity 36 km/hr is :

  • (A) \(6.626\times10^{-34}\) m
  • (B) \(6.626\times10^{-38}\) m
  • (C) \(6.626\times10^{-31}\) m
  • (D) \(6.626\times10^{-30}\) m

Question 63:

Which is the correct order of second ionization potential of \(\mathrm{C, N, O}\) and \(\mathrm{F}\) in the following ?

  • (A) \(\mathrm{O} \gt \mathrm{N} \gt \mathrm{F} \gt \mathrm{C}\)
  • (B) \(\mathrm{O} \gt \mathrm{F} \gt \mathrm{N} \gt \mathrm{C}\)
  • (C) \(\mathrm{F} \gt \mathrm{O} \gt \mathrm{N} \gt \mathrm{C}\)
  • (D) \(\mathrm{C} \gt \mathrm{N} \gt \mathrm{O} \gt \mathrm{F}\)

Question 64:

The shape of \(\mathrm{IF_6^-}\) is :

  • (A) Trigonally distorted octahedron
  • (B) Pyramidal
  • (C) Octahedral
  • (D) Square antiprism

Question 65:

Bond distance in \( HF \) is \( 9.17 \times 10^{-11}\, m \). Dipole moment of \( HF \) is \( 6.10^4 \times 10^{-30}\, Cm \) . The percentage ionic character in \( HF \) will be : (electron charge \( = 1.60 \times 10^{-19}\, C \))

  • (A) \( 61.0\% \)
  • (B) \( 38.0\% \)
  • (C) \( 35.5\% \)
  • (D) \( 41.5\% \)

Question 66:

The correct order of viscosity of the following liquids will be:

  • (A) Water < methyl alcohol < dimethyl ether < glycerol
  • (B) methyl alcohol < glycerol < water < dimethyl ether
  • (C) dimethyl ether < methyl alcohol < water < glycerol
  • (D) glycerol < dimethyl ether < water < methyl alcohol

Question 67:

Which of the following statements/relationships is not correct in thermodynamic changes ?

  • (A) \(\Delta U = 0\) (isothermal reversible expansion of a gas)
  • (B) \(w = -nRT \ln \frac{V_2}{V_1}\) (isothermal reversible expansion of an ideal gas)
  • (C) \(w = nRT \ln \frac{V_2}{V_1}\) (isothermal reversible expansion of an ideal gas)
  • (D) For a system of constant volume heat involved directly changes to internal energy.

Question 68:

\({(1) \,N_2(g) +3H_2(g)<=> 2NH_3(g), K_1}\)
\({(2) \,N_2(g) +O_2(g)<=> 2NHO(g), K_2}\) 
\({(3) \,H_2(g) +\frac{1}{2}O_2(g)<=> H_2O(g), K_3}\) 
The equation for the equilibrium constant of the reaction 
\({2NH_3(g) +\frac{5}{2}O_2(g)<=> 2NO(g), 3H_2O(g)}\), \((K_4)\) in terms of \(K_1\) and \(K_3\) is:

  • (A) \( \frac{K_{1}.K_{2}}{K_{3}} \)
  • (B) \( \frac{K_{1}.K^{2}_{3}}{K_{2}} \)
  • (C) \( K_1K_2K_3 \)
  • (D) \( \frac{K_{2}.K^{3}_{3}}{K_{1}} \)

Question 69:

What is the pH of a \(10^{-4}\ \mathrm{M\ OH^-}\) solution at 330 K, if \(K_w\) at 330 K is \(10^{-13.6}\) ?

  • (A) 4
  • (B) 9.0
  • (C) 10
  • (D) 9.6

Question 70:

The numbers of protons, electrons and neutrons in a molecule of heavy water are respectively :

  • (A) 8, 10, 11
  • (B) 10, 10, 10
  • (C) 10, 11, 10
  • (D) 11, 10, 10

Question 71:

Equimolar solutions of the following compounds are prepared separately in water. Which will have the lowest pH value ?

  • (A) \( BeCl_2 \)
  • (B) \( SrCl_2 \)
  • (C) \( CaCl_2 \)
  • (D) \( MgCl_2 \)

Question 72:

Monocarboxylic acids are functional isomers of:

  • (A) Ethers
  • (B) Amines
  • (C) Esters
  • (D) Alcohols

Question 73:

In a face centred cubic lattice, atoms of \( A \) form the comer points and atoms of \( B \) form the face centred points. If two atoms of \( A \) are missing from the comer points, the formula of the ionic compound is :

  • (A) \( AB_3 \)
  • (B) \( AB_4 \)
  • (C) \( A_2B_5 \)
  • (D) \( AB_2 \)

Question 74:

Vapour pressure of pure benzene is \( 119 \) torr and that of toluene is \( 37.0 \) torr at the same temperature. Mole fraction of toluene in vapour phase which is in equilibrium with a solution of benzene and toluene having a mole fraction of toluene \( 0.50 \), will be :

  • (A) \( 0.137 \)
  • (B) \( 0.237 \)
  • (C) \( 0.435 \)
  • (D) \( 0.205 \)

Question 75:

Given :
\(E^\circ_{\frac{1}{2}\mathrm{Cl_2/Cl^-}} = 1.36\ \mathrm{V},\ E^\circ_{\mathrm{Cr^{3+}/Cr}} = -0.74\ \mathrm{V}\)
\(E^\circ_{\mathrm{Cr_2O_7^{2-}/Cr^{3+}}} = 1.33\ \mathrm{V},\ E^\circ_{\mathrm{MnO_4^-/Mn^{2+}}} = 1.51\ \mathrm{V}\)
The correct order of reducing power of the species \((\mathrm{Cr, Cr^{3+}, Mn^{2+}}\) and \(\mathrm{Cl^-})\) will be :

  • (A) \(\mathrm{Mn^{2+}} \lt \mathrm{Cl^-} \lt \mathrm{Cr^{3+}} \lt \mathrm{Cr}\)
  • (B) \(\mathrm{Mn^{2+}} \lt \mathrm{Cl^{3+}} \lt \mathrm{Cl^-} \lt \mathrm{Cr}\)
  • (C) \(\mathrm{Cr^{3+}} \lt \mathrm{Cl^-} \lt \mathrm{Mn^{2+}} \lt \mathrm{Cr}\)
  • (D) \(\mathrm{Cr^{3+}} \lt \mathrm{Cl^-} \lt \mathrm{Cr} \lt \mathrm{Mn^{2+}}\)

Question 76:

The rate constant of a zero order reaction is \( 2.0 \times 10^{-2}\, mol \,L^{-1}\, s^{-1} \). If the concentration of the reactant after \( 25 \) seconds is \( 0.5\,M \). What is the initial concentration ?

  • (A) \( 0.5\,M \)
  • (B) \( 1.25\,M \)
  • (C) \( 12.5\,M \)
  • (D) \( 1.0\,M \)

Question 77:

Smoke is an example of :

  • (A) Solid dispersed in solid
  • (B) Gas dispersed in liquid
  • (C) Solid dispersed in gas
  • (D) Gas dispersed in solid

Question 78:

Which has trigonal bipyramidal shape ?

  • (A) \( XeOF_4 \)
  • (B) \( XeO_3 \)
  • (C) \( XeO_3F_2 \)
  • (D) \( XeOF_2 \)

Question 79:

When a small amount of \(\mathrm{KMnO_4}\) is added to concentrated \(\mathrm{H_2SO_4}\), a green oily compound is obtained which is highly explosive in nature. Compound may be :

  • (A) \(\mathrm{MnSO_4}\)
  • (B) \(\mathrm{Mn_2O_7}\)
  • (C) \(\mathrm{MnO_2}\)
  • (D) \(\mathrm{Mn_2O_3}\)

Question 80:

Identify incorrect statement :

  • (A) \(\mathrm{Cu_2O}\) is colourless.
  • (B) Copper (I) compounds are colourless except when colour results from charge transfer.
  • (C) Copper (I) compounds are diamagnetic.
  • (D) \(\mathrm{Cu_2S}\) is black.

Question 81:

The magnetic moment of the complex anion \([\mathrm{Cr(NO)(NH_3)(CN)_4}]^{2-}\) is :

  • (A) 5.91 BM
  • (B) 3.87 BM
  • (C) 1.73 BM
  • (D) 2.82 BM

Question 82:

Identify the incorrect statement:

  • (A) In \((\mathrm{Si_3O_9})^{6-}\), tetrahedral \(\mathrm{SiO_4}\) units share two oxygen atoms.
  • (B) Trialkylchlorosilane on hydrolysis gives \(\mathrm{R_3SiOH}\).
  • (C) \(\mathrm{SiCl_4}\) undergoes hydrolysis to give \(\mathrm{H_4SiO_4}\).
  • (D) \((\mathrm{Si_3O_9})^{6-}\) has cyclic structure.

Question 83:

The order of reactivity of the given haloalkanes towards nucleophile is :

  • (A) \( RI > RBr> RCl \)
  • (B) \( RCl > RBr > RI \)
  • (C) \( RBr > RCl > R \)
  • (D) \( RBr > RI > RCl \)

Question 84:

The reaction of phenol with benzoyl chloride to give phenyl benzoate is known as :

  • (A) Claisen reaction
  • (B) Schotten-Baumann reaction
  • (C) Reimer-Tiemann reaction
  • (D) Gatterman-Koch reaction

Question 85:

Which of the following is the product of aldol condensation?

  • (A)
  • (B)
  • (C)
  • (D)

Question 86:

The order of basicity of amines in gaseous state is:

  • (A) \(\( 1^0 > 2^0 > 3^0 > NH_3 \)\)
  • (B) \(\( 3^0 > 2^0 > NH_3 > 1^? \)\)
  • (C) \(\( 3^0 > 2^0 > 1^0 > NH_3 \)\)
  • (D) \(\( NH_3 > 1^0 > 2^0 > 3^0 \)\)

Question 87:

Which of the following polymer is a polyamide ?

  • (A) Terylene
  • (B) Nylon
  • (C) Rubber
  • (D) Vulcanised rubber

Question 88:

\(\mathrm{H_1}\)-Receptor antagonists is a term associated with :

  • (A) Antiseptics
  • (B) Antihistamins
  • (C) Antacids
  • (D) Analgesics

Question 89:

Glycosidic linkage is actually an :

  • (A) Carbonyl bond
  • (B) Ether bond
  • (C) Ester bond
  • (D) Amide bond

Question 90:

Natural glucose is termed D-glucose because :

  • (A) \( -OH \) on the second carbon is on the right side in Fischer projection
  • (B) \( -OH \) on the sixth carbon is on the right side in Fischer projection
  • (C) \( -OH \) on the fifth carbon is on the right side in Fischer projection
  • (D) It is dextrorotatory

JEE Main 2013 Exam Pattern and Marking Scheme

ParticularsDetails
Exam ModeOnline (Computer-Based Test)
PaperB.E./B.Tech (Paper 1)
Duration3 hours (180 minutes)
Type of QuestionsMultiple Choice Questions (MCQs)
SubjectsMathematics, Physics, Chemistry
Total Questions90 questions (30 per subject)
Total Marks360 marks
Marking Scheme+4 for correct answer & -1 for incorrect answer