JEE Main 2022 July 27 Shift 1 Question Paper is available here with solutions PDF and detailed solutions for every question. NTA conducted the first shift on July 27, 2022, from 9:00 AM to 12:00 PM. The JEE Main 2022 Paper 1 (B.E./B.Tech) question paper includes the following:

  • 90 questions in a 3-hour CBT Mode: 30 each from Mathematics, Physics and Chemistry (75 to be attempted)
  • Section A: 20 multiple choice questions (MCQs) per subject, all compulsory, 4 marks each
  • Section B: 10 numerical value questions per subject, any 5 to be attempted, 4 marks each
  • Marking: +4 for a correct answer, -1 for an incorrect answer, 0 for an unattempted question
  • Maximum marks: 300 (100 per subject)

JEE Main 2022 July 27 Shift 1 Question Paper with Solution PDF

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JEE Main 2022 July 27 Shift 1 Questions with Solutions


Mathematics - Section A (Q1 - Q20)

Question 1:

Let R1 and R2 be two relations defined on ℝ by a R1b ⇔ ab ≥ 0 and aR2b ⇔ a ≥ b. Then,

  • (1) R1 is an equivalence relation but not R2
  • (2) R2 is an equivalence relation but not R1
  • (3) Both R1 and R2 are equivalence relations
  • (4) Neither R1 nor R2 is an equivalence relation

Question 2:

Let
f,g:N = {1} → N be functions defined by
f(a) = α, where α is the maximum of the powers of those primes p such that pα divides a, and g(a) = a + 1, for all a ∈ N – {1}. Then, the function f + g is

  • (1) One-one but not onto
  • (2) Onto but not one-one
  • (3) Both one-one and onto
  • (4) Neither one-one nor onto

Question 3:

Let the minimum value v0 of
v = |z|2+|z-3|2+|z-6i|2,z∈C
is attained at z = z0. Then
\(|2z^2_0-\overline{z}^3_0+3|^2+v^2_0\)
is equal to

  • (1) 1000
  • (2) 1024
  • (3) 1105
  • (4) 1196

Question 4:

Let
A = \(\begin{pmatrix}1 & 2\\ -2 & -5 \end{pmatrix}\)
Let \( \alpha, \beta \in \mathbb{R} \) be such that \( \alpha A^2 + \beta A = 2I \). Then \( \alpha + \beta \) is equal to 

  • (1) –10
  • (2) –6
  • (3) 6
  • (4) 10

Question 5:

The remainder when (2021)2022 + (2022)2021 is divided by 7 is

  • (1) 0
  • (2) 1
  • (3) 2
  • (4) 6

Question 6:

Suppose a1, a2, … an, … be an arithmetic progression of natural numbers. If the ration of the sum of first five terms to the sum of first nine terms of the progression is 5 : 17 and 110 < a15 < 120, then the sum of the first ten terms of the progression is equal to

  • (1) 290
  • (2) 380
  • (3) 460
  • (4) 510

Question 7:

Let ℝ → ℝ be function defined as
f(x) = αsin(\((\frac{π[x]}{2})\)+[2-x],α∈R
where [t] is the greatest integer less than or equal to t.
If lim x→1 f(x) exists, then the value of\(∫_0^4\) f(x)dx
is equal to

  • (1) -1
  • (2) -2
  • (3) 1
  • (4) 2

Question 8:

Let
\(I = ∫^{\frac{π}{3}}_{\frac{π}{4}}(\frac{8sinx-sin2x}{x})dx\)
Then

  • (1) \(\frac{π}{2}<I<\frac{3π}{4}\)
  • (2) \(\frac{π}{5}<I<\frac{5π}{12}\)
  • (3) \(\frac{5π}{12}<I<\frac{\sqrt3}{3}π\)
  • (4) \(\frac{3π}{4}<I<π\)

Question 9:

The area of the smaller region enclosed by the curves y2 = 8x + 4 and
x2+y2+4√3x-4=0
is equal to

  • (1) \(\frac{1}{3}(2-12√3+8π)\)
  • (2) \(\frac{1}{3}(2-12√3+6π)\)
  • (3) \(\frac{1}{3}(4-12√3+8π)\)
  • (4) \(\frac{1}{3}(4-12√3+6π)\)

Question 10:

Let y = y1(x) and y = y2(x) be two distinct solution of the differential equation
\(\frac{dy}{dx} = x+y,\)
with y1(0) = 0 and y2(0) = 1 respectively. Then, the number of points of intersection of y = y1 (x) and y = y2(x) is

  • (1) 0
  • (2) 1
  • (3) 2
  • (4) 3

Question 11:

\(\begin{array}{l}\text{Let}~\vec{a} = \alpha \hat{i} + \hat{j} + \beta \hat{k}~\text{and}~ \vec{b} = 3 \hat{i} + 5\hat{j} + 4 \hat{k}~ \text{be two vectors, such that }\vec{a} \times \vec{b} = -\hat{i} + 9\hat{j} + 12 \hat{k}.\end{array}\)
\(\begin{array}{l}~\text{Then the projection of } \vec{b}-2\vec{a} ~\text{on}~ \vec{b}+ \vec{a}~\text {is equal to}\end{array}\)

  • (1) 2
  • (2) \(\frac{39}{5}\)
  • (3) 9
  • (4) \(\frac{46}{5}\)

Question 12:

Let S be the sample space of all five digit numbers. It p is the probability that a randomly selected number from S, is multiple of 7 but not divisible by 5, then 9p is equal to

  • (1) 1.0146
  • (2) 1.2085
  • (3) 1.0285
  • (4) 1.1521

Question 13:

Let\( A(1, 1), B(-4, 3) \)and \(C(-2, -5)\) be vertices of a triangle ABC, P be a point on side BC, and \(Δ1\) and \(Δ2\) be the areas of triangles APB and ABC, respectively. If \(Δ1 : Δ2 = 4 : 7\), then the area enclosed by the lines AP, AC and the x-axis is

  • (1) \(\frac{1}{4}\)
  • (2) \(\frac{3}{4}\)
  • (3) \(\frac{1}{2}\)
  • (4) 1

Question 14:

If the circle
x2+y2-2gx+6y-19c = 0,g,c∈R
passes through the point (6, 1) and its centre lies on the line x – 2cy = 8, then the length of intercept made by the circle on x-axis is

  • (1) √11
  • (2) 4
  • (3) 3
  • (4) 2√23

Question 15:

Let a function f: ℝ → ℝ be defined as :
\(\begin{array}{l}f(x) = \left\{\begin{matrix}\int_{0}^{x}(5-|t-3|)dt, & x>4 \\x^2 + bx, & x \le4 \\\end{matrix}\right.\end{array}\)
where b ∈ ℝ. If f is continuous at x = 4 then which of the following statements is NOT true?

  • (1) f is not differentiable at x = 4
  • (2) \(f'(3)+f'(5) = \frac{35}{4}\)
  • (3) f is increasing in (-∞, \(\frac{1}{8}\))∪(8,∞)
  • (4) f has local minima at x = \(\frac{1}{8}\)

Question 16:

Let P(a, b) be a point on the parabola y2 = 8x such that the tangent at P passes through the centre of the circle x2 + y2 – 10x – 14y + 65 = 0. Let A be the product of all possible values of a and B be the product of all possible values of b. Then the value of A + B is equal to

  • (1) 0
  • (2) 25
  • (3) 40
  • (4) 65

Question 17:

Let α→ = \(2\^{i}-\^{j}+5\^{k} and b→= α\^{i}+β\^{j}+2\^{k}. If ((α→×b→)×\^{i}).\^{k} \)=\(\frac{ 23}{2}\),then \(|b→×2\^{j}\| \)is equal to

  • (1) 4
  • (2) 5
  • (3) √21
  • (4) √17

Question 18:

Let a vertical tower AB of height 2h stands on a horizontal ground. Let from a point P on the ground a man can see up to height h of the tower with an angle of elevation 2α.
When from P, he moves a distance d in the direction of \(\overrightarrow{AP}\).
he can see the top B of the tower with an angle of elevation α. if \(d = \sqrt7\) h, then tan α is equal to

  • (1) √5-2
  • (2) √3-1
  • (3) √7-2
  • (4) √7-√3

Question 19:

\((p\wedge r)\Leftrightarrow(p\wedge(\sim q))\) is equivalent to \((\sim p)\) when \(r\) is

  • (1) \(p\)
  • (2) \(\sim p\)
  • (3) \(q\)
  • (4) \(\sim q\)

Question 20:

If the plane P passes through the intersection of two mutually perpendicular planes 2x + ky – 5z = 1 and 3kx – ky + z = 5, k < 3 and intercepts a unit length on positive x-axis, then the intercept made by the plane P on the y-axis is

  • (1) \(\frac{1}{11}\)
  • (2) \(\frac{5}{11}\)
  • (3) 6
  • (4) 7

Mathematics - Section B (Q21 - Q30)

Question 21:

For k ∈ R, let the solution of the equation
\(\cos\left(\sin^{-1}\left(x \cot\left(\tan^{-1}\left(\cos\left(\sin^{-1}\right)\right)\right)\right)\right) = k, \quad 0 < |x| < \frac{1}{\sqrt{2}}\)
Inverse trigonometric functions take only principal values. If the solutions of the equation x2 – bx – 5 = 0 are
\(\frac{1}{α^2}+\frac{1}{β^2} \)and \(\frac{α}{β}\)
, then b/k2 is equal to_____.


Question 22:

The mean and variance of 10 observation were calculated as 15 and 15 respectively by a student who took by mistake 25 instead of 15 for one observation. Then, the correct standard deviation is ________.


Question 23:

An ellipse
\(E:\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1\)
passes through the vertices of the hyperbola
\(H:\frac{x^2}{49} - \frac{y^2}{64} = -1\)
Let the major and minor axes of the ellipse E coincide with the transverse and conjugate axes of the hyperbola H, respectively. Let the product of the eccentricities of E and H be 1/2. If the length of the latus rectum of the ellipse E, then the value of 113l is equal to _____.


Question 24:

Let y = y(x) be the solution curve of the differential equation
\(\sin(2x^2) \log_e(\tan(x^2)) \,dy + (4xy - 4\sqrt{2}x\sin(x^2 - \frac{\pi}{4})) \,dx = 0, \quad 0 < x < \sqrt{\frac{\pi}{2}}\)
which passes through the point \((\sqrt{\frac{π}{6}},1)\). Then \(|y(\sqrt{\frac{π}{3}})|\)
is equal to _______.


Question 25:

Let
\(f(x) = 2x^2 - x - 1\ and\ S = \{ n \in \mathbb{Z} : |f(n)| \leq 800 \}\)
Then, the value of ∑n∈S f(n) is equal to ________.


Question 26:

Let S be the set containing all 3 × 3 matrices with entries from {-1, 0, 1}. The total number of matrices A ∈ S such that the sum of all the diagonal elements of AT A is 6 is ________.


Question 27:

If the length of the latus rectum of the ellipse x2 + 4y2 + 2x + 8y – λ = 0 is 4, and l is the length of its major axis, then λ + l is equal to ________.


Question 28:

Let
\(S = \left\{z∈C : z^2+\overline{z} = 0 \right\}\). Then \(∑_{z∈S}(Re(z)+Im(z))\)
is equal to____.


Question 29:

Let the line
\(\frac{x - 3}{7} = \frac{y - 2}{-1} = \frac{z - 3}{-4}\)
intersect the plane containing the lines
\(\frac{x - 4}{1} = \frac{y + 1}{-2} = \frac{z}{1}\) and \(4ax-y+5z-7a = 0 = 2x-5y-z-3, a∈R\)
at the point P(α, β, γ). Then the value of α + β + γ equals _____.


Question 30:

Let M and N be the number of points on the curve y5 – 9xy + 2x = 0, where the tangents to the curve are parallel to x-axis and y-axis, respectively. Then the value of M + N equals ________.


Physics - Section A (Q31 - Q50)

Question 31:

Choose the correct answer.

1. A torque meter is calibrated to reference standards of mass, length and time each with 5% accuracy. After calibration, the measured torque with this torque meter will have net accuracy of

  • (1) 15%
  • (2) 25%
  • (3) 75%
  • (4) 5%

Question 32:

A bullet is shot vertically downwards with an initial velocity of 100 m/s from a certain height. Within 10s, the bullet reaches the ground and instantaneously comes to rest due to the perfectly inelastic collision. The velocity-time curve for total time t = – 20s will be 

(Take g = 10 m/s2)

  • (1)

    A bullet is shot vertically downwards with an initial velocity of 100 m/s from a certain height.

  • (2)

    A torque meter is calibrated to reference standards of mass, length and time each with 5% accuracy.

  • (3)

    A torque meter is calibrated to reference standards of mass, length and time each with 5% accuracy

  • (4)

    A torque meter is calibrated to reference standards of mass, length and time each with 5% accuracy


Question 33:

Sand is being dropped from a stationary dropper at a rate of 0.5 kgs–1 on a conveyor belt moving with a velocity of 5 ms–l. The power needed to keep the belt moving with the same velocity will be

  • (1) 1.25 W
  • (2) 2.5 W
  • (3) 6.25 W
  • (4) 12.5 W

Question 34:

A bag is gently dropped on a conveyor belt moving at a speed of 2 m/s. The coefficient of friction between the conveyor belt and bag is 0.4. Initially the bag slips on the belt before it stops due to friction. The distance travelled by the bag on the belt during slipping motion, is 

[Take g = 10 m/s2]

  • (1) 2 m
  • (2) 0.5 m
  • (3) 3.2 m
  • (4) 0.8 ms

Question 35:

Two cylindrical vessels of equal cross-sectional area 16 cm2 contain water upto heights 100 cm and 150 cm respectively. The vessels are interconnected so that the water levels in them become equal. The work done by the force of gravity during the process, is [Take, density of water = 103 kg/m3 and g = 10 ms–2]

  • (1) 0.25 J
  • (2) 1 J
  • (3) 8 J
  • (4) 12 J

Question 36:

Two satellites A and B, having masses in the ratio 4 : 3, are revolving in circular orbits of radii 3r and 4r respectively around the earth. The ratio of total mechanical energy of A to B is

  • (1) 9 : 16
  • (2) 16 : 9
  • (3) 1 : 1
  • (4) 4 : 3

Question 37:

If K1 and K2 are the thermal conductivities, L1 and L2 are the lengths and A1 and A2 are the cross sectional areas of steel and copper rods respectively such that \(\frac{K_2}{K_1}=9,\frac{A_1}{A_2}=2,\frac{L_1}{L_2}=2.\) 

Then, for the arrangement as shown in the figure, the value of temperature T of the steel-copper junction in the steady state will be

  • (1) 18°C
  • (2) 14°C
  • (3) 45°C
  • (4) 150°C

Question 38:

Read the following statements:

A. When small temperature difference between a liquid and its surrounding is doubled, the rate of loss of heat of the liquid becomes twice.

B. Two bodies P and Q having equal surface areas are maintained at temperature 10°C and 20°C. The thermal radiation emitted in a given time by P and Q are in the ratio 1 : 1.15.

C. A carnot Engine working between 100 K and 400 K has an efficiency of 75%.

D. When small temperature difference between a liquid and its surrounding is quadrupled, the rate of loss of heat of the liquid becomes twice.

Choose the correct answer from the options given below

  • (1) A, B, C only
  • (2) A, B only
  • (3) A, C only
  • (4) B, C, D only

Question 39:

Same gas is filled in two vessels of the same volume at the same temperature. If the ratio of the number of molecules is 1 : 4, then

A. The r.m.s. velocity of gas molecules in two vessels will be the same.

B. The ratio of pressure in these vessels will be 1 : 4.

C. The ratio of pressure will be 1 : 1.

D. The r.m.s. velocity of gas molecules in two vessels will be in the ratio of 1 : 4.

Choose the correct answer from the options given below.

  • (1) A and C only
  • (2) B and D only
  • (3) A and B only
  • (4) C and D only

Question 40:

Two identical positive charges Q each are fixed at a distance of 2a apart from each other. Another point charge q0 with mass m is placed at midpoint between two fixed charges. For a small displacement along the line joining the fixed charges, the charge q0 executes SHM. The time period of oscillation of charge q0 will be

  • (1) \(\sqrt{\frac{4\pi^3ε0rna^3}{q0Q}}\)
  • (2) \(\sqrt{\frac{qoQ}{4\pi^3εrna^3}}\)
  • (3) \(\sqrt{\frac{2\pi^2ε_0rna^3}{q0Q}}\)
  • (4) \(\sqrt{\frac{8\pi^3ε_0rna^3}{q0Q}}\)

Question 41:

Two sources of equal emfs are connected in series. This combination is connected to an external resistance R. The internal resistances of the two sources are r1 and r2 (r1 > r2). If the potential difference across the source of internal resistance r1 is zero, then the value of R will be :

  • (1) \(r_1-r_2\)
  • (2) \(\frac{r_1r_2}{r_1+r_2}\)
  • (3) \(\frac{r_1+r_2}{2}\)
  • (4) \(r_2-r_1\)

Question 42:

A direct current of 4 A and an alternating current of peak value 4 A flow through resistance of 3 Ω and 2 Ω respectively. The ratio of heat produced in the two resistances in same interval of time will be :

  • (1) 3 : 2
  • (2) 3 : 1
  • (3) 3 : 4
  • (4) 4 : 3

Question 43:

A beam of light travelling along X-axis is described by the electric field Ey = 900sin ω(t – x/c). The ratio of electric force to magnetic force on a charge q moving along Y-axis with a speed of 3 × 107 ms–1 will be :
(Given speed of light = 3 × 108 ms–1)

  • (1) 1 : 1
  • (2) 1 : 10
  • (3) 10 : 1
  • (4) 1 : 2

Question 44:

A microscope was initially placed in air (refractive index 1). It is then immersed in oil (refractive index 2). For a light whose wavelength in air is λ, calculate the change of microscope’s resolving power due to oil and choose the correct option.

  • (1) Resolving power will be\( \frac{1}{4}\) in the oil than it was in the air.
  • (2) Resolving power will be twice in the oil than it was in the air.
  • (3) Resolving power will be four times in the oil than it was in the air.
  • (4) Resolving power will be \(\frac{1}{2}\) in the oil than it was in the air.

Question 45:

An electron (mass m) with an initial velocity
\(\vec{v}=v_0\hat{i}(v_0>0)\)
is moving in an electric field
\(\vec{E}=E_0\hat{i}(E_0>0)\)
where E0 is constant. If at t = 0 de Broglie wavelength is
\(λ_0=\frac{ℎ}{mv_0}\)
, then its de Broglie wavelength after time t is given by

  • (1) \(λ_0\)
  • (2) \(λ_0\left(1+\frac{eE_0t}{mv_0}\right)\)
  • (3) \(λ_0t\)
  • (4) \(\frac{λ_0}{\left(1+\frac{eE_0t}{mv_0}\right)}\)

Question 46:

A logic gate circuit has two inputs A and B and output Y. The voltage waveforms of A, B and Y are shown below.
 

Fig. Logic gate circuit


The logic gate circuit is :

  • (1) AND gate
  • (2) OR gate
  • (3) NOR gate
  • (4) NAND gate

Question 47:

Two bar magnets oscillate in a horizontal plane in earth’s magnetic field with time periods of 3 s and 4 s respectively. If their moments of inertia are in the ratio of 3 : 2, then the ratio of their magnetic moments will be :

  • (1) 2 : 1
  • (2) 8 : 3
  • (3) 1 : 3
  • (4) 27 : 16

Question 48:

A magnet hung at 45° with magnetic meridian makes an angle of 60° with the horizontal. The actual value of the angle of dip is

  • (1) \(\tan^{-1}\left(\sqrt{\frac{3}{2}}\right)\)
  • (2) \(\tan^{-1}\left(\sqrt{6}\right)\)
  • (3) \(\tan^{-1}\left(\sqrt{\frac{2}{3}}\right)\)
  • (4) \(\tan^{-1}\left(\sqrt{\frac{1}{2}}\right)\)

Question 49:

What is the half-life period of a radioactive material if its activity drops to 1/16 th of its initial value in 30 years?

  • (1) 9.5 years
  • (2) 8.5 years
  • (3) 7.5 years
  • (4) 10.5 years

Question 50:

At a particular station, the TV transmission tower has a height of 100 m. To triple its coverage range, height of the tower should be increased to

  • (1) 200 m
  • (2) 300 m
  • (3) 600 m
  • (4) 900 m

Physics - Section B (Q51 - Q60)

Question 51:

In a meter bridge experiment, for measuring unknown resistance ‘S’, the null point is obtained at a distance 30 cm from the left side as shown at point D. If R is 5.6 kΩ, then the value of unknown resistance ‘S’ will be ___Ω.

Fig. Meter Bridge

Question 52:

The one division of main scale of Vernier callipers reads 1mm and 10 divisions of Vernier scale is equal to the 9 division on main scale. When the two jaws of the instrument touch each other, the zero of the Vernier lies to the right of zero of the main scale and its fourth division coincides with a main scale division. When a spherical bob is tightly placed between the two jaws, the zero of the Vernier scale lies in between 4.1 cm and 4.2 cm and 6th Vernier division coincides with a main scale division. The diameter of the bob will be ___ × 10–2 cm.


Question 53:

Two beams of light having intensities I and 4I interfere to produce a fringe pattern on a screen. The phase difference between the two beams are π/2 and π/3 at points A and B, respectively. The difference between the resultant intensities at the two points is xI. The value of x will be ___.


Question 54:

To light, a W, 100 V lamp is connected, in series with a capacitor of capacitance 
\(\frac{50}{π\sqrt{x}}\mu F\) with \(200 V\), 50 Hz AC source.
The value of x will be ___.


Question 55:

A 1 m long copper wire carries a current of 1 A. If the cross section of the wire is 2.0 mm2 and the resistivity of copper is 1.7 × 10–8 Ω, the force experienced by moving electron in the wire is ___ × 10–23N.
(Charge on electron = 1.6 × 10–19C)


Question 56:
A long cylindrical volume contains a uniformly distributed charge of density ρ cm–3.
 The electric field inside the cylindrical volume at a distance \(x=\frac{2ε_0}{ρ} m\) from its axis is _______ Vm–1
Fig.

Question 57:

A mass 0.9 kg, attached a horizontal spring, executes SHM with an amplitude A1. When this mass passes through its mean position, then a smaller mass of 124 g is placed over it and both masses move together with amplitude A2. If the ratio A1/A2 is α/(α – 1), then the value of α will be _____.


Question 58:

A square aluminium (shear modulus is 25 × 109 Nm–2) slab of side 60 cm and thickness 15 cm is subjected to a shearing force (on its narrow face) of 18.0 × 104 N. The lower edge is riveted to the floor. The displacement of the upper edge is ______μm.


Question 59:

A pulley of radius 1.5 m is rotated about its axis by a force F = (12t – 3t2) N applied tangentially (while t is measured in seconds). If moment of inertia of the pulley about its axis of rotation is 4.5 kg m2, the number of rotations made by the pulley before its direction of motion is reversed, will be K/π. The value of K is ________.


Question 60:

A ball of mass m is thrown vertically upward. Another ball of mass 2 m is thrown at an angle θ with the vertical. Both the balls stay in air for the same period of time. The ratio of the heights attained by the two balls respectively is 1/x. The value of x is _______.


Chemistry - Section A (Q61 - Q80)

Question 61:

\(250\) \(g\) solution of \(D-glucose\) in water contains 10.8% of carbon by weight. The molality of the solution is nearest to (Given: Atomic Weights are, \(H, 1 u; C, 12 u; O, 16 u\))

  • (1) 1.03
  • (2) 2.06
  • (3) 3.09
  • (4) 5.40

Question 62:

Given below are two statements.
Statement I: \(O_2, Cu^{2+}, \;and\; Fe^{3+}\) are weakly attracted by magnetic field and are magnetized in the same direction as magnetic field.
Statement II: \(NaCl\) and \(H_2O\) are weakly magnetized in opposite directions to the magnetic field.
In the light of the above statements, choose the most appropriate answer from the options given below.

  • (1) Both Statement I and Statement II are correct.
  • (2) Both Statement I and Statement II are incorrect.
  • (3) Statement I is correct but Statement II is incorrect.
  • (4) Statement I is incorrect but Statement II is correct.

Question 63:

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Energy of 2s orbital of hydrogen atom is greater than that of 2s orbital of lithium.
Reason R : Energies of the orbitals in the same subshell decrease with increase in the atomic number.
In the light of the above statements, choose the correct answer from the options given below.

  • (1) Both A and R are true and R is the correct explanation of A.
  • (2) Both A and R are true but R is NOT the correct explanation of A.
  • (3) A is true but R is false.
  • (4) A is false but R is true.

Question 64:

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Activated charcoal adsorbs \(SO_2\) more efficiently than \(CH_4\).
Reason R: Gases with lower critical temperatures are readily adsorbed by activated charcoal.
In the light of the above statements, choose the correct answer from the options given below.

  • (1) Both A and R are correct and R is the correct explanation of A.
  • (2) Both A and R are correct but R is NOT the correct explanation of A.
  • (3) A is correct but R is not correct.
  • (4) A is not correct but R is correct.

Question 65:

Boiling point of a 2% aqueous solution of a non-volatile solute A is equal to the boiling point of 8% aqueous solution of a non-volatile solute B. The relation between molecular weights of A and B is

  • (1) \(M_A = 4M_B\)
  • (2) \(M_B = 4M_A\)
  • (3) \(M_A = 8M_B\)
  • (4) \(M_B = 8M_A\)

Question 66:

The incorrect statement is

  • (1) The first ionization enthalpy of K is less than that of Na and Li.
  • (2) Xe does not have the lowest first ionization enthalpy in its group.
  • (3) The first ionization enthalpy of element with atomic number 37 is lower than that of the element with atomic number 38.
  • (4) The first ionization enthalpy of Ga is higher than that of the d-block element with atomic number 30.

Question 67:

Given below are two statements.
Statement I: Iron (III) catalyst, acidified \(K_2Cr_2O_7\) and neutral \(KMnO_4\) have the ability to oxidise \(I^–\) to \(I_2\) independently.
Statement II: Manganate ion is paramagnetic in nature and involves \(pπ – pπ\) bonding.
In the light of the above statements, choose the correct answer from the options given below.

  • (1) Both Statement I and Statement II are true
  • (2) Both Statement I and Statement II are false
  • (3) Statement I is true but Statement II is false
  • (4) Statement I is false but Statement II is true

Question 68:

The total number of \(Mn=O\) bonds in \(Mn_2O_7\) is ___.

  • (1) 4
  • (2) 5
  • (3) 6
  • (4) 3

Question 69:

Given below are two statements: one is labelled as Assertion A and, the other is labelled as Reason R.
Assertion A: [6] Annulene, [8] Annulene and cis-[10] Annulene, are respectively aromatic, not-aromatic and aromatic.
Reason R: Planarity is one, of the requirements of aromatic systems.
In the light of the above statements, choose the most appropriate answer from the options given below.

  • (1) Both A and R are correct and R is the correct explanation of A
  • (2) Both A and R are correct but R is NOT the correct explanation of A.
  • (3) A is correct but R is not correct.
  • (4) A is not correct but R is correct.

Question 70:

Chemical Reaction
In the above reaction product ’P’ is

  • (1) Product 1
  • (2) Product 2
  • (3) Product 3
  • (4) Product 4

Question 71:

A sugar ‘X’ dehydrates very slowly under acidic conditions to give furfural which on further reaction with resorcinol gives the coloured product after some time. Sugar ‘X’ is
sugar ‘X’ dehydrates very slowly under acidic condition

  • (1) Aldopentose
  • (2) Aldotetrose
  • (3) Oxalic acid
  • (4) Ketotetrose

Question 72:

In Carius method of estimation of halogen, 0.45 g of an organic compound gave 0.36 g of AgBr. Find out the percentage of bromine in the compound.
(Molar masses: AgBr = 188 g mol–1; Br = 80 g mol–1)

  • (1) 34.04%
  • (2) 40.04%
  • (3) 36.03%
  • (4) 38.04%

Question 73:

Match List I with List II.
 

List-IList-II
A. Benzene sulphonyl chlorideI. Test for primary amines
B. Hoffmann bromamide reactionII. Anti Saytzeff
C. Carbylamine reactionIII. Hinsberg reagent
D. Hoffmann orientationIV. Known reaction of Isocyamates

Choose the correct answer from the options given below:

  • (1) A-IV, B-III, C-II, D-I
  • (2) A-IV, B-II, C-I, D-II
  • (3) A-III, B-IV, C-I, D-II
  • (4) A-IV, B-III, C-I, D-II

Question 74: Which of the following methods are not used to refine any metal?
  1. Liquation
  2. Calcination
  3. Electrolysis
  4. Leaching
  5. Distillation
Choose the correct answer from the options given below :
  • (1) B & D only
  • (2) A, B, D & E only
  • (3) B, D & E only
  • (4) A, C & E only

Question 75:

Given below are two statements.
Statement I : Hydrogen peroxide can act as an oxidizing agent in both acidic and basic conditions.
Statement II : Density of hydrogen peroxide at 298 K is lower than that of \(D_2O\).
In the light of the above statements, choose the correct answer from the options given below :

  • (1) Both Statement I and Statement II are true
  • (2) Both Statement I and Statement II are false
  • (3) Statement I is true but Statement II is false
  • (4) Statement I is false but Statement II is true

Question 76:

Given below are two statements.
Statement I : The chlorides of Be and Al have Cl-bridged structure. Both are soluble in organic solvents and act as Lewis bases.
Statement II : Hydroxides of Be and Al dissolve in excess alkali to give beryllate and aluminate ions.
In the light of the above statements, choose the correct answer from the options given below.

  • (1) Both Statement I and Statement II are true
  • (2) Both Statement I and Statement II are false
  • (3) Statement I is true but Statement II is false
  • (4) Statement I is false but Statement II is true

Question 77:

Which oxoacid of phosphorous has the highest number of oxygen atoms present in its chemical formula?

  • (1) Pyrophosphorus acid
  • (2) Hypophosphoric acid
  • (3) Phosphoric acid
  • (4) Pyrophosphoric acid

Question 78: Match List I with List II.
List I Pollutant List II Disease/ sickness
A. Sulphate (> 500 ppm)I. Methemoglobinemia
B. Nitrate (> 50 ppm)II. Brown mottling of teeth
C. Lead (> 50 ppb)III. Laxative effect
D. Fluoride (> 2ppm)IV. Kidney damage
Choose the coned answer from the options given below:
  • (1) A-IV, B-I, C-II, D-III
  • (2) A-III, B-I, C-IV, D-II
  • (3) A-II, B-IV, C-I, D-III
  • (4) A-II, B-IV, C-III, D-I

Question 79:
Match List-I with List-I
List-I List II
A. Phenol-formaldehyde resinIGlyptal
B. The copolymer of 1,3-butadiene and styreneIINovolac
C.Polyester of glycol and phthalic acidIIIBuna-S
D.Polyester of glycol and terephthalic acidIVDacron
Choose the correct answer from the option given below:
  • (1) A-II, B-III, C-IV, D-I
  • (2) A-II, B-III, C-I, D-IV
  • (3) A-II, B-I, C-III, D-IV
  • (4) A-III, B-II, C-IV, D-I

Question 80:

Match the List I  with List II

List I

 

List II

AIAnti-depressant
BII550 times sweeter than cane sugar
CIIINarcotic analgesic
DIVAntiseptic

Choose the correct answer from the options given below:

  • (1) A-IV, B-III, C-II, D-I
  • (2) A-III, B-I, C-II, D-IV
  • (3) A-III, B-IV, C-I, D-II
  • (4) A-III, B-I, C-IV, D-II

Chemistry - Section B (Q81 - Q90)

Question 81:

20 mL of 0.02 M K2Cr2O7 solution is used for the titration of 10 mL of Fe2+ solution in the acidic medium. The molarity of Fe2+ solution is ______×10–2 M. (Nearest integer)


Question 82:

2NO + 2H2 → N2 + 2H2O
The above reaction has been studied at 800 °C. The related data is given in the table below.
The order of the reaction with respect to NO is ___.


Question 83:

Amongst the following, the number of oxide(s) which are paramagnetic in nature is
Na2O, KO2, NO2, N2O, ClO2, NO, SO2, Cl2O


Question 84:

The molar heat capacity for an ideal gas at constant pressure is 20.785 J K–1 mol–1. The change in internal energy is 5000 J upon heating it from 300 K to 500 K. The number of moles of the gas at constant volume is _____. (Nearest integer)
(Given : R = 8.314 JK-1mol-1).


Question 85:

According to MO theory, number of species/ions from the following having identical bond order is ___.
CN-, NO+, O2, O+2, O2+2


Question 86:

At 310 K, the solubility of CaF2 in water is 2.34 ×10–3 g/100 mL. The solubility product of CaF2 is _____ × 10–8 (mol/L)3.
(Given molar mass : CaF2 = 78 g mol–1).


Question 87:

The conductivity of a solution of complex with formula CoCl3(NH3)4 corresponds to 1 : 1 electrolyte, then the primary valency of central metal ion is ______.


Question 88:

In the titration of KMnO4 and oxalic acid in acidic medium, the change in oxidation number of carbon at the end point is _____.


Question 89:

Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of (+) isomer is +30°. The optical purity is _______%.


Question 90:

In the following reaction,
the % yield for reaction I is 60% and that of reaction II is 50%. The overall yield of the complete reaction is _______%. [Nearest integer].

the % yield for reaction I is 60% and that of reaction II is 50%.

JEE Main 2022 Exam Pattern and Marking Scheme

ParticularsDetails
Exam ModeOnline (Computer-Based Test)
PaperB.E./B.Tech (Paper 1)
Duration3 hours (180 minutes)
Type of QuestionsMultiple Choice Questions (MCQs) + Numerical Value Questions
SubjectsMathematics, Physics, Chemistry
Total Questions90 questions (75 to be attempted)
Total Marks300 marks
Marking Scheme+4 for correct answer & -1 for incorrect MCQ and Numerical Value-based Questions

JEE Main 2022 July 27 Shift 1 Difficulty Level

As per the initial students’ reaction, the paper was reported as moderate in terms of overall difficulty. Mathematics was found tough and lengthy, Physics as moderate and Chemistry easy.

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