JEE Main 2019 B.E./B.Tech Question Paper with Answer Keys (January 11, 2019- Forenoon Session)

The area (in sq. units) of the region bounded by the curve \(x^2 = 4y\) and the straight line \(x = 4y - 2\) is :

• (1) \(\frac{3}{4}\)
• (2) \(\frac{5}{4}\)
• (3) \(\frac{7}{8}\)
• (4) \(\frac{9}{8}\)

The straight line \(x + 2y = 1\) meets the coordinate axes at A and B. A circle is drawn through A, B and the origin. Then the sum of perpendicular distances from A and B on the tangent to the circle at the origin is :

• (1) \(4\sqrt{5}\)
• (2) \(\frac{\sqrt{5}}{2}\)
• (3) \(2\sqrt{5}\)
• (4) \(\frac{\sqrt{5}}{4}\)

The sum of an infinite geometric series with positive terms is 3 and the sum of the cubes of its terms is \(\frac{27}{19}\). Then the common ratio of this series is :

• (1) \(\frac{4}{9}\)
• (2) \(\frac{1}{3}\)
• (3) \(\frac{2}{3}\)
• (4) \(\frac{2}{9}\)

If \( \int \frac{\sqrt{1-x^{2}}}{x^{4}} dx = A \left(x\right)\left(\sqrt{1-x^{2}}\right)^{m} + C \) , for a suitable chosen integer \(m\) and a function \(A(x)\), where \(C\) is a constant of integration then \((A(x))^m\) equals :

• (1) \(\frac{-1}{3x^3}\)
• (2) \(\frac{-1}{27 x^9}\)
• (3) \(\frac{1}{9 x^4}\)
• (4) \(\frac{1}{27 x^6}\)

Two integers are selected at random from the set {1, 2,...., 11}. Given that the sum of selected numbers is even, the conditional probability that both the numbers are even is :

• (1) \(\frac{2}{5}\)
• (2) \(\frac{1}{2}\)
• (3) \(\frac{3}{5}\)
• (4) \(\frac{7}{10}\)

A square is inscribed in the circle \(x^2 + y^2 - 6x + 8y - 103 = 0\) with its sides parallel to the coordinate axes. Then the distance of the vertex of this square which is nearest to the origin is :

• (1) \(\sqrt{137}\)
• (2) \(6\)
• (3) \(\sqrt{41}\)
• (4) \(13\)

If one real root of the quadratic equation \(81x^2 + kx + 256 = 0\) is cube of the other root, then a value of \(k\) is

• (1) \(-81\)
• (2) \(-300\)
• (3) \(100\)
• (4) \(144\)

The maximum value of the function \(f(x) = 3x^3 - 18x^2 + 27x - 40\) on the set \(S = \{x \in \mathbb{R} : x^2 + 30 \le 11x\}\) is :

• (1) \(-222\)
• (2) \(-122\)
• (3) \(122\)
• (4) \(222\)

Let $A=\left(\begin{array}{ccc}0& 2q& r\\ p& q& -r\\ p& -q& r\end{array}\right)$. If $A{A}^T=I_3$, then $|p|$ is:

• (1) $\frac{1}{\sqrt{2}}$
• (2) $\frac{1}{\sqrt{5}}$
  
  
• (3) $\frac{1}{\sqrt{6}}$
  
  
• (4) $\frac{1}{\sqrt{3}}$

Let \(f : \mathbb{R} \to \mathbb{R}\) be defined by \(f(x) = \frac{x}{1+x^2},\ x \in \mathbb{R}\). Then the range of f is :

• (1) \(\left[-\frac{1}{2}, \frac{1}{2}\right]\)
• (2) \(\mathbb{R} - \left[-\frac{1}{2}, \frac{1}{2}\right]\)
• (3) \((-1, 1) - \{0\}\)
• (4) \(\mathbb{R} - [-1, 1]\)

If the system of linear equations
2x + 2ay + az = 0
2x + 3by + bz = 0
2x + 4cy + cz = 0,
where a, b, c \( \in \) R are non-zero distinct; has a non-zero solution, then:

• (1) \( {1 \over a},{1 \over b},{1 \over c} \) are in A.P.
• (2) a + b + c = 0
• (3) a, b, c are in G.P.
• (4) a,b,c are in A.P.

If \(y(x)\) is the solution of the differential equation \(\frac{dy}{dx} + \left(\frac{2x+1}{x}\right)y = e^{-2x},\ x \gt 0\), where \(y(1) = \frac{1}{2}e^{-2}\), then

• (1) \(y(\log_e 2) = \log_e 4\)
• (2) \(y(x)\) is decreasing in \((0, 1)\)
• (3) \(y(\log_e 2) = \frac{\log_e 2}{4}\)
• (4) \(y(x)\) is decreasing in \(\left(\frac{1}{2}, 1\right)\)

Let \(f(x) = \begin{cases} -1, & -2 \le x \lt 0 \\ x^2 - 1, & 0 \le x \le 2 \end{cases}\) and \(g(x) = |f(x)| + f(|x|)\). Then, in the interval \((-2, 2)\), g is :

• (1) non continuous
• (2) differentiable at all points
• (3) not differentiable at two points
• (4) not differentiable at one point

Let \([x]\) denote the greatest integer less than or equal to \(x\). Then \(\lim_{x \to 0} \frac{\tan(\pi \sin^2 x) + \left(|x| - \sin(x[x])\right)^2}{x^2}\)

• (1) equals \(\pi + 1\)
• (2) equals 0
• (3) does not exist
• (4) equals \(\pi\)

The sum of the real values of \(x\) for which the middle term in the binomial expansion of \(\left(\frac{x^3}{3} + \frac{3}{x}\right)^8\) equals 5670 is :

• (1) \(0\)
• (2) \(8\)
• (3) \(6\)
• (4) \(4\)

The value of the integral \(\int \limits^{2}_{-2} \frac{\sin^{2}x}{\left[\frac{x}{\pi}\right] + \frac{1}{2}} dx \) (where [x] denotes the greatest integer less than \(^{20}C_r\) or equal to x) is :

• (1) 4
• (2) 4 - sin 4
• (3) sin 4
• (4) 0

Let \(a_1, a_2, ....., a_{10}\) be a G.P. If \(\frac{a_3}{a_1} = 25 \), then \(\frac{a_9}{a_5}\) equals :

• (1) \(2(5^2)\)
• (2) \(4(5^2)\)
• (3) \(5^4\)
• (4) \(5^3\)

If \(x\log_e(\log_e x) - x^2 + y^2 = 4\ (y \gt 0)\), then \(\frac{dy}{dx}\) at \(x = e\) is equal to :

• (1) \(\frac{(1+2e)}{2\sqrt{4+e^2}}\)
• (2) \(\frac{(1+2e)}{\sqrt{4+e^2}}\)
• (3) \(\frac{(2e-1)}{2\sqrt{4+e^2}}\)
• (4) \(\frac{e}{\sqrt{4+e^2}}\)

Let \(f_k(x) = \frac{1}{k}\left(\sin^k x + \cos^k x\right)\) for \(k = 1, 2, 3, \dots\) Then for all \(x \in \mathbb{R}\), the value of \(f_4(x) - f_6(x)\) is equal to

• (1) \(\frac{1}{4}\)
• (2) \(\frac{5}{12}\)
• (3) \(\frac{-1}{12}\)
• (4) \(\frac{1}{12}\)

The outcome of each of \(30\) items was observed; \(10\) items gave an outcome \(\frac{1}{2} - d\) each, \(10\) items gave outcome \(\frac{1}{2}\) each and the remaining 10 items gave outcome \(\frac{1}{2} + d\) each. If the variance of this outcome data is \(\frac{4}{3}\) then |d| equals :

• (1) \(2\)
• (2) \(\frac{\sqrt{5}}{2}\)
• (3) \(\frac{2}{3}\)
• (4) \(\sqrt{2}\)

Let \(\vec{a} = \hat{i} + 2\hat{j} + 4\hat{k}\), \(\vec{b} = \hat{i} + \lambda\hat{j} + 4\hat{k}\) and \(\vec{c} = 2\hat{i} + 4\hat{j} + (\lambda^2 - 1)\hat{k}\) be coplanar vectors. Then the non-zero vector \(\vec{a} \times \vec{c}\) is :

• (1) \(-10\hat{i} - 5\hat{j}\)
• (2) \(-10\hat{i} + 5\hat{j}\)
• (3) \(-14\hat{i} + 5\hat{j}\)
• (4) \(-14\hat{i} - 5\hat{j}\)

Let \(\left(-2 - \frac{1}{3}i\right)^3 = \frac{x + iy}{27}\ (i = \sqrt{-1})\), where x and y are real numbers, then \(y - x\) equals :

• (1) \(-85\)
• (2) \(85\)
• (3) \(-91\)
• (4) \(91\)

Equation of a common tangent to the parabola \(y^2 = 4x\) and the hyperbola \(xy = 2\) is :

• (1) \(x + y + 1 = 0\)
• (2) \(4x + 2y + 1 = 0\)
• (3) \(x - 2y + 4 = 0\)
• (4) \(x + 2y + 4 = 0\)

The value of \(r\) for which \({}^{20}C_r\,{}^{20}C_0 + {}^{20}C_{r-1}\,{}^{20}C_1 + {}^{20}C_{r-2}\,{}^{20}C_2 + \ldots + {}^{20}C_0\,{}^{20}C_r\) is maximum, is

• (1) 20
• (2) 15
• (3) 10
• (4) 11

The plane containing the line \(\frac{x-3}{2} = \frac{y+2}{-1} = \frac{z-1}{3}\) and also containing its projection on the plane \(2x + 3y - z = 5\), contains which one of the following points ?

• (1) \((-2, 2, 2)\)
• (2) \((2, 2, 0)\)
• (3) \((2, 0, -2)\)
• (4) \((0, -2, 2)\)

If tangents are drawn to the ellipse \(x^2 + 2y^2 = 2\) at all points on the ellipse other than its four vertices then the mid points of the tangents intercepted between the coordinate axes lie on the curve :

• (1) \(\frac{x^2}{2} + \frac{y^2}{4} = 1\)
• (2) \(\frac{1}{2x^2} + \frac{1}{4y^2} = 1\)
• (3) \(\frac{1}{4x^2} + \frac{1}{2y^2} = 1\)
• (4) \(\frac{x^2}{4} + \frac{y^2}{2} = 1\)

In a triangle, the sum of lengths of two sides is \(x\) and the product of the lengths of the same two sides is \(y\). If \(x^2 - c^2 = y\), where \(c\) is the length of the third side of the triangle, then the circumradius of the triangle is :

• (1) \(\frac{y}{\sqrt{3}}\)
• (2) \(\frac{c}{3}\)
• (3) \(\frac{c}{\sqrt{3}}\)
• (4) \(\frac{3}{2}y\)

If \(q\) is false and \(p \wedge q \leftrightarrow r\) is true, then which one of the following statements is a tautology ?

• (1) \(p \wedge r\)
• (2) \((p \vee r) \rightarrow (p \wedge r)\)
• (3) \(p \vee r\)
• (4) \((p \wedge r) \rightarrow (p \vee r)\)

The direction ratios of normal to the plane through the points \((0, -1, 0)\) and \((0, 0, 1)\) and making an angle \(\frac{\pi}{4}\) with the plane \(y - z + 5 = 0\) are :

• (1) \(2, -1, 1\)
• (2) \(2\sqrt{3}, 1, -1\)
• (3) \(\sqrt{2}, 1, -1\)
• (4) \(\sqrt{2}, -\sqrt{2}\)

Two circles with equal radii are intersecting at the points \((0, 1)\) and \((0, -1)\). The tangent at the point \((0, 1)\) to one of the circles passes through the centre of the other circle. Then the distance between the centres of these circles is :

• (1) \(1\)
• (2) \(\sqrt{2}\)
• (3) \( 2 \sqrt{2}\)
• (4) \(2\)

A slab is subjected to two forces \(\vec{F_1}\) and \(\vec{F_2}\) of same magnitude \(F\) as shown in the figure. Force \(\vec{F_2}\) is in XY-plane while force \(\vec{F_1}\) acts along z-axis at the point \((2\hat{i} + 3\hat{j})\). The moment of these forces about point O will be :

• (1) \((3\hat{i} - 2\hat{j} - 3\hat{k})F\)
• (2) \((3\hat{i} + 2\hat{j} - 3\hat{k})F\)
• (3) \((3\hat{i} + 2\hat{j} + 3\hat{k})F\)
• (4) \((3\hat{i} - 2\hat{j} + 3\hat{k})F\)

In a Wheatstone bridge (see fig.), Resistances \(P\) and \(Q\) are approximately equal. When \(R = 400\ \Omega\), the bridge is balanced. On interchanging \(P\) and \(Q\), the value of \(R\), for balance, is \(405\ \Omega\). The value of \(X\) is close to :

• (1) 402.5 ohm
• (2) 401.5 ohm
• (3) 403.5 ohm
• (4) 404.5 ohm

Three charges \(Q\), \(+q\) and \(+q\) are placed at the vertices of a right-angle isosceles triangle as shown below. The net electrostatic energy of the configuration is zero, if the value of \(Q\) is :

• (1) \(\frac{-q}{1 + \sqrt{2}}\)
• (2) \(+q\)
• (3) \(-2q\)
• (4) \(\frac{-\sqrt{2}\,q}{\sqrt{2} + 1}\)

In the circuit shown, the switch \(S_1\) is closed at time \(t = 0\) and the switch \(S_2\) is kept open. At some later time \((t_0)\), the switch \(S_1\) is opened and \(S_2\) is closed. The behavious of the current \(I\) as a function of time \('t'\) is given by :

• (1)
• (2)
• (3)
• (4)

The resistance of the meter bridge \(AB\) is given figure is \(4\Omega\) . With a cell of emf \(\varepsilon = 0.5 \;V \) and rheostat resistance \(R_h = 2 \; \Omega\) the null point is obtained at some point \(J\). When the cell is replaced by another one of emf \(\varepsilon = \varepsilon_2\) the same null point \(J\) is found for \(R_h = 6 \; \Omega\). The emf \(\varepsilon_2\) is;

• (1) 0.6 V
• (2) 0.5 V
• (3) 0.3 V
• (4) 0.4 V

A particle is moving along a circular path with a constant speed of \(10\ \mathrm{ms^{-1}}\). What is the magnitude of the change in velocity of the particle, when it moves through an angle of \(60^\circ\) around the centre of the circle?

• (1) zero
• (2) \(10\ \mathrm{m/s}\)
• (3) \(10\sqrt{2}\ \mathrm{m/s}\)
• (4) \(10\sqrt{3}\ \mathrm{m/s}\)

A rigid diatomic ideal gas undergoes an adiabatic process at room temperature,. The relation between temperature and volume of this process is \(TV^x\) = constant, then \(x\) is :

• (1) \(\frac{5}{3}\)
• (2) \(\frac{2}{5}\)
• (3) \(\frac{2}{3}\)
• (4) \(\frac{3}{5}\)

In the figure shown below, the charge on the left plate of the \(10 \; \mu F\) capacitor is \(-30 \; \mu C\) . The charge on the right plate of the \(6 \; \mu F\) capacitor is :

• (1) \( - 18 \; \mu C \)
• (2) \( - 12 \; \mu C \)
• (3) \(+ 12 \; \mu C \)
• (4) \(+ 18 \; \mu C \)

An equilateral triangle ABC is cut from a thin solid sheet of wood. (see figure) D, E and F are the mid-points of its sides as shown and G is the centre of the triangle. The moment of inertia of the triangle about an axis passing through G and perpendicular to the plane of the triangle is \(I_0\). If the smaller triangle DEF is removed from ABC, the moment of inertia of the remaining figure about the same axis is I. then :

• (1) \(I = \frac{I_0}{4}\)
• (2) \(I = \frac{15}{16}I_0\)
• (3) \(I = \frac{9}{16}I_0\)
• (4) \(I = \frac{3}{4}I_0\)

The given graph shows variation (with distance \(r\) form centre) of :

• (1) Electric field of a uniformly charged sphere
• (2) Electric field of a uniformly charged spherical shell
• (3) Potential of a uniformly charged sphere
• (4) Potential of a uniformly charged spherical shell

The variation of refractive index of a crown glass thin prism with wavelength of the incident light is shown. Which of the following graphs is the correct one, if \(D_m\) is the angle of minimum deviation?

• (1)
• (2)
• (3)
• (4)

In the given circuit, the current through zener diode is :

• (1) \(5.5 \,mA\)
• (2) \(6.7 \,mA\)
• (3) \(2.5 \,mA\)
• (4) \(3.3\, mA\)

The force of interaction between two atoms is given by \(F = \alpha\beta\exp\left(-\frac{x^2}{\alpha kt}\right)\); where \(x\) is the distance, \(k\) is the Boltzmann constant and \(T\) is temperature and \(\alpha\) and \(\beta\) are two constants. The dimension of \(\beta\) is :

• (1) \(M^2L^2T^{-2}\)
• (2) \(M^2LT^{-4}\)
• (3) \(MLT^{-4}\)
• (4) \(M^0L^2LT^{-4}\)

There are two long co-axial solenoids of same length \(l\). the inner and outer coils have radii \(r_1\) and \(r_2\) and number of turns per unit length \(n_1\) and \(n_2\) respectively. The rate of mutual inductance to the self-inductance of the inner-coil is :

• (1) \(\frac{n_{2}}{n_{1}}. \frac{r^{2}_{2}}{r_{1}^{2}} \)
• (2) \(\frac{n_{2}}{n_{1}}. \frac{r_{1}}{r_{2}} \)
• (3) \(\frac{n_1}{n_2}\)
• (4) \(\frac{n_2}{n_1}\)

An object is at a distance of 20 m from a convex lens of focal length 0.3 m. The lens forms an image of the object. If the object moves away from the lens at a speed of 5 m/s, the speed and direction of the image will be :

• (1) \(1.16\times 10^{-3}\) m/s towards the lens
• (2) \(2.26\times 10^{-3}\) m/s away from the lens
• (3) \(3.22\times 10^{-3}\) m/s towards the lens
• (4) \(0.92\times 10^{-3}\) m/s away from the lens

A hydrogen atom, initially in the ground state is excited by absorbing a photon of wavelength 980\(\mathring A \). The radius of the atom in the excited state, it terms of Bohr radius \(a_0\), will be : (\(h_c\) = \(12500\, eV - \mathring A \))

• (1) \(9a_0\)
• (2) \(25a_0\)
• (3) \(4a_0\)
• (4) \(16a_0\)

A liquid of density \(\rho\) is coming out of a hose pipe of radius \(a\) with horizontal speed \(v\) and hits a mesh. 50% of the liquid passes through the mesh unaffected. 25% looses all of its momentum and 25% comes back with the same speed. The resultant pressure on the mesh will be :

• (1) \(\frac{3}{4}\rho v^2\)
• (2) \(\frac{1}{4}\rho v^2\)
• (3) \(\frac{1}{2}\rho v^2\)
• (4) \(\rho v^2\)

A satellite is revolving in a circular orbit at a height ' \(h\)' from the earth's surface (radius of earth \(R ; h < < R\)). The minimum increase in its orbital velocity required, so that the satellite could escape from the earth?s gravitational field, is close to : (Neglect the effect of atmosphere.)

• (1) \(\sqrt{2\,gR}\)
• (2) \(\sqrt{g\,R}\)
• (3) \(\sqrt{g\,R / 2 }\)
• (4) \(\sqrt{gR} ( \sqrt{2} - 1 ) \)

Ice at \(-20^{\circ} C\) os added tp \(50\, g\) of water at \(40^{\circ}C\). When the temperature of the mixture reaches \(0^{\circ}C\), it is found that \(20\, g\) of ice is still unmelted. The amount of ice added to the water was close to (Specific heat of water = \(4.2 \; J/g/^{\circ}C\)) Specific heat of Ice = \(2.1 \; J/g/^{\circ}C\) Heat of fusion of water at \(0^{\circ}C = 334 \; J/g\))

• (1) 50 g
• (2) 40 g
• (3) 60 g
• (4) 100 g

If the de Broglie wavelength of an electron is equal to the \(10^{-3}\) times the wavelength of a photon of frequency \(6 \times 10^{14}\) Hz, then the speed of electron is equal to : (Speed of light = \(3 \times 10^{8}\) m/s, Planck's constant = \(6.63 \times 10^{-34}\) J.s, Mass of electron = \(9.1 \times 10^{-31}\) kg)

• (1) \(1.7 \times 10^{6}\) m/s
• (2) \(1.45 \times 10^{6}\) m/s
• (3) \(1.1 \times 10^{6}\) m/s
• (4) \(1.8 \times 10^{6}\) m/s

A body of mass \(1\, kg\) falls freely from a height of \(100\, m\) on a platform of mass \(3\, kg\) which is mounted on a spring having spring constant \(k = 1.25 \times 10^6 \; N/m\). The body sticks to the platform and the spring's maximum compression is found to be \(x\). Given that \(g = 10 \; ms^{-2}\), the value of \(x\) will be close to :

• (1) 4 cm
• (2) 8 cm
• (3) 80 cm
• (4) 40 cm

Two equal resistance when connected in series to a battery, consume electric power of \(60\, W\). If these resistances are now connected in parallel combination to the same battery, the electric power consumed will be :

• (1) 60 W
• (2) 240 W
• (3) 30 W
• (4) 120 W

An electromagnetic wave of intensity 50 Wm\(^{-2}\) enters in a medium of refractive index 'n' without any loss. The ratio of the magnitudes of electric, and the ratio of the magnitudes of magnetic fields of the wave before and after entering into the medium are respectively, given by:

• (1) \(\left(\frac{1}{\sqrt{n}}, \frac{1}{\sqrt{n}}\right)\)
• (2) \(\left(\sqrt{n}, \sqrt{n}\right)\)
• (3) \(\left(\sqrt{n}, \frac{1}{\sqrt{n}}\right)\)
• (4) \(\left(\frac{1}{\sqrt{n}}, \sqrt{n}\right)\)

Equation of travelling wave on a stretched string of linear density \(5\, g/m\) is \(y\, =\, 0.03\, sin(450\, t - 9x)\) where distance and time are measured is SI units. The tension in the string is :

• (1) 10 N
• (2) 12.5 N
• (3) 7.5 N
• (4) 5 N

A body is projected at t = 0 with a velocity 10 ms\(^{-1}\) at an angle of \(60^\circ\) with the horizontal. The radius of curvature of its trajectory at t = 1s is R. neglecting air resistance and taking acceleration due to gravity g = 10 ms\(^{-2}\), the value of R is :

• (1) 2.8 m
• (2) 5.1 m
• (3) 2.5 m
• (4) 10.3 m

In an experiment, electrons are accelerated, from rest, by applying a voltage of 500 V. Calculate the radius of the path if a magnetic field 100 mT is then applied. [Charge of the electron = \(1.6 \times 10^{-19}\) C Mass of the electron = \(9.1 \times 10^{-31}\) kg]

• (1) \(7.5 \times 10^{-4}\) m
• (2) \(7.5 \times 10^{-3}\) m
• (3) 7.5 m
• (4) \(7.5 \times 10^{-2}\) m

In a Young's double slit experiment, the path difference, at a certain point on the screen, between two interfering waves is \(\frac{1}{8}\) th of wavelength. The ratio of the intensity at this point to that at the centre of a bright fringe is close to :

• (1) 0.94
• (2) 0.85
• (3) 0.74
• (4) 0.80

A gas mixture consists of 3 moles of oxygen and 5 moles of argon at temperature T. considering only translational and rotational modes, the total internal energy of the system is :

• (1) 12 RT
• (2) 20 RT
• (3) 4 RT
• (4) 15 RT

A particle undergoing simple harmonic motion has time dependent displacement given by \(x(t) = A \sin \frac{\pi t}{90}\). The ratio of kinetic to potential energy of this particle at \(t\, =\, 210\, s\) will be :

• (1) 2
• (2) \(\frac{1}{9}\)
• (3) 3
• (4) 1

An amplitude modulated signal is given by \(V(t) = 10[1 + 0.3 \cos(2.2 \times 10^4)] \sin(5.5 \times 10^5t)\). Here t is in seconds. The sideband frequencies (in kHz) are, [Given \(\pi = 22/7\)]

• (1) 1785 and 1715
• (2) 892.5 and 857.5
• (3) 89.25 and 85.75
• (4) 178.5 smf 171.5

Consider the reaction
\(\mathrm{N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)}\)

The equilibrium constant of the above reaction is \(K_p\). If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by (Assume that \(P_{NH_3} \ll P_{total}\) at equilibrium)

• (1) \(\frac{3^{3/2}K_P^{1/2}P^2}{4}\)
• (2) \(\frac{K_P^{1/2}P^2}{4}\)
• (3) \(\frac{3^{3/2}K_P^{1/2}P^2}{16}\)
• (4) \(\frac{K_P^{1/2}P^2}{16}\)

The correct order of the atomic radii of \(C, Cs, Al\) and \(S\) is :

• (1) \(S < C < Al < Cs\)
• (2) \(S < C < Cs < Al\)
• (3) \(C < S < Cs < Al\)
• (4) \(C < S < Al < Cs\)

Two blocks of the same metal having same mass and at temperature \(T_1\) and \(T_2\), respectively, are brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy, \(\Delta S\), for this process is :

• (1) \(2C_p \ln\left[\frac{(T_1+T_2)^{1/2}}{T_1T_2}\right]\)
• (2) \(2C_p \ln\left[\frac{(T_1+T_2)}{2T_1T_2}\right]\)
• (3) \(C_p \ln\left[\frac{(T_1+T_2)^2}{4T_1T_2}\right]\)
• (4) \(2C_p \ln\left[\frac{(T_1+T_2)}{4T_1T_2}\right]\)

The freezing point of a diluted milk sample is found to be \(-0.2^\circ\)C, while it should have been \(-0.5^\circ\)C for pure milk. How much water has been added to pure milk to make the diluted sample?

• (1) 1 cup of water to 2 cups of pure milk
• (2) 2 cups of water to 3 cups of pure milk
• (3) 3 cups of water to 2 cups of pure milk
• (4) 1 cup of water to 3 cups of pure milk

The major product of the following reaction is :

• (1)
• (2)
• (3)
• (4)

• (1) A \(\rightarrow\) (R); (B) \(\rightarrow\) (P); (C) \(\rightarrow\) (S)
• (2) A \(\rightarrow\) (Q); (B) \(\rightarrow\) (R); (C) \(\rightarrow\) (S)
• (3) A \(\rightarrow\) (Q); (B) \(\rightarrow\) (P); (C) \(\rightarrow\) (R)
• (4) A \(\rightarrow\) (S); (B) \(\rightarrow\) (R); (C) \(\rightarrow\) (P)

The major product of the following reaction is :

• (1)
• (2)
• (3)
• (4)

Heat treatment of muscular pain involves radiation of wavelength of about \(900\, nm\). Which spectral line of H-atom is suitable for this purpose ? \([R_H = 1 \times 10^5 \; cm^{-1}, h = 6.6 \times 10^{-34} \; Js, c = 3 \times 10^8 \; ms^{-1}]\)

• (1) Paschen, \(5\to 3\)
• (2) Paschen, \(\infty \to 3\)
• (3) Lyman, \(\infty \to 1\)
• (4) Balmer, \(\infty \to 2\)

The element that usually does NOT show variable oxidation states is :

• (1) V
• (2) Cu
• (3) Sc
• (4) ti

Which of the following is an aromatic compound?

• (1)
• (2)
• (3)
• (4)

Among the following compounds, which one is found in RNA ?

• (1)
• (2)
• (3)
• (4)

For the chemical reaction \(\mathrm{X \rightleftharpoons Y}\), the standard reaction Gibbs energy depends on temperature \(T\) (in K) as \(\Delta_r G^\circ\) (in kJ mol\(^{-1}\)) = \(120 - \frac{3}{8}T\).
The major component of the reaction mixture at \(T\) is :

• (1) Y if \(T = 300\) K
• (2) Y if \(T = 280\) K
• (3) X if \(T = 350\) K
• (4) X if \(T = 315\) K

A \(10\, mg\) effervescent tablet contianing sodium bicarbonate and oxalic acid releases \(0.25\, ml\) of \({CO_2}\) at \(T\) = \(298.15\, K\) and \(p = 1\) bar. If molar volume of \({CO_2}\) is \(25.0\, L\) under such condition, what is the percentage of sodium bicarbonate in each tablet ? [Molar mass of \({NaHCO_3 = 84 \; g \; mol^{-1}}\)]

• (1) 16.8
• (2) 8.4
• (3) 0.84
• (4) 33.6

An organic compound is estimated through Duma's method and was found to evolve 6 moles of \(\mathrm{CO_2}\), 4 moles of \(\mathrm{H_2O}\) and 1 mole of nitrogen gas. The formula of the compound is :

• (1) \(\mathrm{C_6H_8N}\)
• (2) \(\mathrm{C_6H_8N_2}\)
• (3) \(\mathrm{C_{12}H_8N}\)
• (4) \(\mathrm{C_{12}H_8N_2}\)

• (1) \(\mathrm{Ag^{+}/Ag}\)
• (2) \(\mathrm{Fe^{3+}/Fe^{2+}}\)
• (3) \(\mathrm{Au^{3+}/Au}\)
• (4) \(\mathrm{Fe^{2+}/Fe}\)

The major product of the following reaction is :

• (1)
• (2)
• (3)
• (4)

The major product of the following reaction is

• (1)
• (2)
• (3)
• (4)

If a reaction follows the Arrhenius equation, the plot \(\ln k\) vs \(\frac{1}{RT}\) gives straight line with a gradient (\(-y\)) unit.
The energy required to active the reactant is :

• (1) \(y\) unit
• (2) \(y/R\) unit
• (3) \(yR\) unit
• (4) \(-y\) unit

• (1) (A)-(iii); (B)-(iv); (C)-(i); (D)-(ii)
• (2) (A)-(iv); (B)-(iii); (C)-(i); (D)-(ii)
• (3) (A)-(i); (B)-(ii); (C)-(iii); (D)-(iv)
• (4) (A)-(ii); (B)-(i); (C)-(iv); (D)-(iii)

An example of solid sol is :

• (1) Butter
• (2) Gem stones
• (3) Paint
• (4) Hair cream

The chloride that CANNOT get hydrolysed is :

• (1) \(\mathrm{SnCl_4}\)
• (2) \(\mathrm{SiCl_4}\)
• (3) \(\mathrm{PbCl_4}\)
• (4) \(\mathrm{CCl_4}\)

NaH is an example of :

• (1) Electron-rich hydride
• (2) Molecular hydride
• (3) Saline hydride
• (4) Metallic hydride

• (1) (A) \(\rightarrow\) (R); (B) \(\rightarrow\) (P); (C) \(\rightarrow\) (R)
• (2) (A) \(\rightarrow\) (R); (B) \(\rightarrow\) (P); (C) \(\rightarrow\) (S)
• (3) (A) \(\rightarrow\) (Q); (B) \(\rightarrow\) (P); (C) \(\rightarrow\) (R)
• (4) (A) \(\rightarrow\) (Q); (B) \(\rightarrow\) (R); (C) \(\rightarrow\) (S)

The concentration of dissolved oxygen \((DO)\) in cold water can go upto :

• (1) 10 ppm
• (2) 14 ppm
• (3) 16 ppm
• (4) 8 ppm

The polymer obtained from the following reaction is :

• (1)
• (2)
• (3)
• (4)

Peroxyacetyl nitrate (PAN), an eye irritant is produced by :

• (1) classical smog
• (2) acid rain
• (3) photochemical smog
• (4) organic waste

The amphoteric hydroxide is :

• (1) \(\ce{Ca(OH)2}\)
• (2) \(\ce{Be(OH)2}\)
• (3) \(\ce{Sr(OH)2}\)
• (4) \(\ce{Mg(OH)2}\)

The correct statements among (a) to (d) regarding \(\mathrm{H_2}\) as a fuel are :
(a) It produces less pollutants than petrol.
(b) A cylinder of compressed dihydrogen weighs \(\sim\) 30 times more than a petrol tank producing the same amount of energy.
(c) Dihydrogen is stored in tanks of metal alloys like \(\mathrm{NaNi_5}\).
(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 KJ, respectively.

• (1) (a) and (c) only
• (2) (b) and (d) only
• (3) (a), (b) and (c) only
• (4) (b), (c) and (d) only

A solid having density of \(9 \times 10^3 \; kg \; m^{-3}\) forms face centred cubic crystals of edge length \(200 \sqrt{2}\) pm. What is the molar mass of the solid ? [Avogadro constant \(\simeq 6 \times 10^{23} \, mol^{-1}, \pi \simeq 3]\)

• (1) \({0.0216 \; kg \; mol^{-1}}\)
• (2) \({0.0305 \; kg \; mol^{-1}}\)
• (3) \({0.4320\; kg \; mol^{-1}}\)
• (4) \({0.0432\; kg \; mol^{-1}}\)

• (1) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
• (2) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
• (3) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
• (4) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)