JEE Main Atomic Structure PYQ PDF is a free, 48-page resource containing 223 questions from the 2002-2026 papers. The chapter recorded 26 questions across the 2026 papers, with a reported weightage of 5.47% in the referenced database.

The PDF includes 53 questions on quantum numbers and the shapes of orbitals, 39 questions on the Bohr model, and 164 MCQs alongside 59 numerical-value questions. Questions are arranged from newest to oldest to help students practise recent exam patterns and revise key concepts.

The PDF Contains:

223 Questions48 Page5.47%
↑30.00% Weightage in 2026
2002-2026 years covered

Atomic Structure is a chapter in Class 11 Chemistry. Every question carries its exam date and shift. The PDF holds questions only, with options as printed. Worked solutions for the questions are under "View Solution" further down this page.

JEE Main Atomic Structure Weightage by Year

As per JEE Main Atomic Structure weightage from past years, students can expect about 1 question from this chapter in most shifts. It took 5.47% of the Chemistry questions in 2026, the highest in this window, up from 3.33% in 2022.

YearQuestionsAverage per ShiftWeightage in ChemistryChange in Weightage
2026261.375.47%+30.00%
2025201.054.21%+26.32%
2024201.003.33%−11.11%
2023271.123.75%+12.50%
2022231.003.33%+8.33%

The 2021 papers add 24 more questions, and the years before that add 83. Weightage is the chapter's share of all Chemistry questions in the bank for that year.

Topic-Wise Questions and PDFs

Four topics carry the chapter. Quantum numbers and orbitals, the Bohr model, the quantum mechanical model and the hydrogen spectrum make up 156 of the 223 questions, about 70%. Each topic also has its own PDF if you want to drill one area.

TopicQuestionsPDF SizeDownload
Quantum numbers and shapes of s, p and d orbitals532.008 MBDownload PDF
Bohr model of a hydrogen atom391.992 MBDownload PDF
Quantum mechanical model of the atom and atomic orbitals332.142 MBDownload PDF
Spectrum of the hydrogen atom311.935 MBDownload PDF
Photoelectric effect212.086 MBDownload PDF
Dual nature of matter and de Broglie's relationship181.915 MBDownload PDF
Nature of electromagnetic radiation151.888 MBDownload PDF
Heisenberg uncertainty principle91.863 MBDownload PDF
Rules for filling electrons in orbitals: Aufbau principle, Pauli's exclusion principle and Hund's rule31.821 MBDownload PDF
Electronic configuration of elements and stability of half-filled and completely filled orbitals11.819 MBDownload PDF

Question Types and Difficulty

Roughly three in four questions are single-answer MCQs. The 59 numerical-value questions all come from 2020 onwards.

Question TypeQuestionsShare
Single-correct MCQ16473.5%
Numerical value5926.5%
Total223100%

By the difficulty tag in our question bank, 129 questions are easy and 75 are medium. Only 2 are hard, and 17 carry no tag.

How to Practise Atomic Structure

Begin with the Bohr model and the hydrogen spectrum, 39 and 31 questions that rest on a handful of formulas. Then take the 53 questions on quantum numbers and orbital shapes and the 33 on the quantum mechanical model.

Finish with the photoelectric effect, de Broglie's relationship, electromagnetic radiation and the uncertainty principle, 63 questions in all, plus the 4 on filling rules and electronic configuration. Redo any you missed after a day.

Related JEE Main Chemistry Resources

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Atomic Structure JEE Main Previous Year Questions with Solutions and WeightageRead and download
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JEE Main Chemistry Atomic Structure PYQsRead and download

Video: Atomic Structure PYQs One Shot

Source: Vedantu JEE Made Ejee

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