Thermodynamics and the Gaseous State are essential topics in Physical Chemistry for JEE Mains. The Thermodynamics and the Gaseous State in JEE Mains contribute approximately 8-10% weighatge to the total Chemistry marks, with 2-3 questions usually asked from each topic.

Most common topics and questions of Thermodynamics and the Gaseous State from JEE Main and JEE Advanced are laws of thermodynamics, entropy, enthalpy, Gibbs free energy, ideal gas laws, and real gases. There are 25 questions in the Chemistry paper of JEE Main.

These concepts are vital for solving problems related to heat exchange, chemical reactions, and energy efficiency. Similarly, the Gaseous State focuses on the properties and behavior of gases, including gas laws, Ideal Gas Law, Kinetic Molecular Theory, and real gases.

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Listed below is the list of Thermodynamics and the Gaseous State questions with detailed solutions asked in JEE Main.

Thermodynamics & Gaseous State- JEE Main Previous Years Question Paper with solution pdf

Question 1.

Q1. Thermodynamics JEE Main

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Question 2.

The possible number of stereoisomers for 5-phenylpent-4-en-2-ol is: ______________ 

[JEE Main 2025]

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Question 3.

Q3. Thermodynamics JEE Main

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Question 4.

Q4. Thermodynamics JEE Mains

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Question 5.

Q5. Thermodynamics JEE Mains

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Question 6.

The elemental composition of a compound is 54.2%C, 9.2%H, and 36.6%O. If the molar mass of the compound is 132 g/mol, the molecular formula of the compound is: [JEE Main 2025]

A. C6H12O6
B. C6H12O3
C. C4H9O3
D. C4H8O2

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Question 7.

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be: [JEE Main 2025]

A. Green → Pale Blue → Blue → Violet
B. Pale Blue → Blue → Green → Violet
C. Pale Blue → Blue → Violet → Green
D. Violet → Blue → Pale Blue → Green

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Question 8.

Which of the following mixing of 1M base and 1M acid leads to the largest increase in temperature? [JEE Main 2025]

A. 30 mL CH₃COOH and 30 mL NaOH
B. 45 mL CH₃COOH and 25 mL NaOH
C. 50 mL HCl and 20 mL NaOH
D. 30 mL HCl and 30 mL NaOH

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Question 9.

In the given structure, the number of sp and sp² hybridized carbon atoms present respectively are: [JEE Main 2025]

Q9. Thermodynamics JEE Main

A. 3 and 5
B. 4 and 5
C. 3 and 6
D. 4 and 6

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Question 10.

Q10. Thermodynamics JEE Main

A. 348 K and 300 J
B. 378 K and 500 J
C. 378 K and 300 J
D. 368 K and 500 J

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Question 11.

If

C(diamond) → C(graphite) + X kJ mol⁻¹
C(diamond) + O₂(g) → CO(g) + Y kJ mol⁻¹
C(graphite) + O₂(g) → CO(g) + Z kJ mol⁻¹

At constant temperature. Then: [JEE Main 2025]

A. X = Y + Z
B. X − Y = Z
C. X = Y − Z
D. X = Z

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Question 12.

Q12. Thermodynamics JEE Main

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Question 13.

The molarity of a 70%(mass/mass) aqueous solution of a monobasic acid (X) is: [JEE Main 2025]

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Question 14.

Q14. Thermodynamics JEE Main

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Question 15.

Q15. Thermodynamics JEE Mains
  1. 8
  2. 12
  3. -12
  4. -8

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JEE Main Chemistry Paper Pattern

JEE Main Chemistry Paper Pattern


JEE Main Chemistry Chapter - Wise Weightage

The JEE Main 2025 Chemistry Chapter is divided into 3 sections i.e. Inorganic Chemistry, Organic Chemistry, and Physical Chemistry.

The major topics in Inorganic Chemistry are, Transition Elements, Coordination Compounds, and Periodic Table and p-Block Elements account for 9.9% (3-4 questions). Whereas, Atomic Structure, Chemical Bonding, and Environmental Chemistry account for 6.6% each, or about 2 questions.

In Organic Chemistry, the Biomolecules, Carbohydrates, and Carboxylic Acids chapters hold 6.6% weightage each. Aromatic Compounds and Hydrocarbons sections have 3.3%, so organic chemistry is an important subject.

The Physical Chemistry chapters of Chemical Kinetics and Electrochemistry hold 3.3% each or 1 question each. They are compulsory but have less weightage as compared to inorganic and organic chemistry.

JEE Main 2025 Chemistry Chapter-Wise Weightage

Chapter Approximate Weightage (%) Number of Questions
Transition Elements and Coordination Compounds 9.9% 3-4
Periodic Table and p-Block Elements 9.9% 3-4
Atomic Structure 6.6% 2
Nuclear and Environmental Chemistry 6.6% 2
Chemical Bonding and Molecular Structure 6.6% 2
Chemical and Ionic Equilibrium 6.6% 2
Thermodynamics and the Gaseous State 6.6% 2
Biomolecules 6.6% 2
Carbohydrates, Amino Acids, and Polymers 6.6% 2
Carboxylic Acids and their Derivatives 6.6% 2
Aromatic Compounds 6.6% 2
General Organic Chemistry 3.3% 1
Stereochemistry 3.3% 1
Hydrocarbons 3.3% 1
Alkyl Halides 3.3% 1
Solutions and Colligative Properties 3.3% 1
Electrochemistry 3.3% 1
Chemical Kinetics 3.3% 1
Redox Reactions 3.3% 1
Mole Concept 3.3% 1
Solid State and Surface Chemistry 3.3% 1
Transition Elements 3.3% 1
Coordination Compounds 3.3% 1
General Principles of Metallurgy 3.3% 1
  • The inorganic Chemistry section has the highest weightage of 35% in the JEE Main Chemistry Paper.
    Organic Chemistry has a weightage of approx 20-25%.
    Physical Chemistry is about 15-20% of the total questions.

JEE Main Last 5 Year Chemistry Papers Pdf

JEE Main 2024 Chemistry Question Paper Session 1

Exam Date Question Paper Solution PDF
JEE Main 2024 Feb 1 Shift 2 Chemistry Question Paper Download Check Solution
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JEE Main 2024 Jan 31 Shift 2 Chemistry Question Paper Download Check Solution
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JEE Main 2024 Jan 27 Shift 2 Chemistry Question Paper Download Check Solution
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JEE Main 2024 Chemistry Question Paper Session 2

Exam Date and Shift Question Paper Solution PDF
JEE Main 2024 April 4 Shift 1 Chemistry Question Paper Download Check Solution
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JEE Main 2023 Chemistry Question Paper Session 2

Exam Date Chemistry Question Paper 2023
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Chemistry 15 April Shift 1 Question Paper Check Here

JEE Main 2023 Chemistry Question Paper Session 1

Exam Date and Shift Chemistry Question Paper 2023
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Chemistry 1 February Shift 1 Question Paper Check Here
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JEE Main 2022 Chemistry Question Paper with Solution PDF- Phase 2

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JEE Main 2022 Chemistry Question Paper with Solution PDF- Phase 1

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June 26 Shift 1 Check Here
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JEE Main 2021 Chemistry Question Paper with Solution (Session 4- August)- Download PDF

Exam Date Shift/ Slot Question Paper PDF
August 26 Shift 1 Check Here
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August 27 Shift 1 Check Here
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August 31 Shift 1 Check Here
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JEE Main 2021 Chemistry Question Paper with Solution (Session 3- July)- Download PDF

Exam Date Shift/ Slot Question Paper PDF
July 22 Shift 2 Check Here
July 25 Shift 1 Check Here
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July 27 Shift 1 Check Here
August 3 Shift 1 Check Here
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JEE Main 2021 Chemistry Question Paper with Solution (Session 2- March)- Download PDF

Exam Date Shift/ Slot Question Paper PDF
March 16 Shift 1 Check Here
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March 17 Shift 1 Check Here
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JEE Main 2021 Chemistry Question Paper with Solution (Session 1- February)- Download PDF

Exam Date Shift/ Slot Question Paper PDF
February 24 Shift 1 Check Here
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February 26 Shift 1 Check Here
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JEE Main 2020 Chemistry Question Paper with Solutions (Session 2- September)- Download PDF

Exam Date Shift/ Slot JEE Main Question Paper PDF
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September 3 Shift 1 Check Here
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September 4 Shift 1 Check Here
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September 5 Shift 1 Check Here
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JEE Main 2020 Chemistry Question Paper with Solutions (Session 1- January)- Download PDF

Exam Date Shift/ Slot JEE Main Question Paper PDF
January 8 Shift 1 Check Here
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January 9 Shift 1 Check Here
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Important Topics Related toThermodynamics and the Gaseous State

Frequently Asked Questions

Q1. Is thermodynamics tough in JEE?

Answer: The difficulty level of Thermodynamics is rated as moderately difficult in JEE.

  • In JEE Mains, thermodynamics has about 5–6% weightage of the total marks, which is about 2–3 questions from the topics of the first law, entropy, enthalpy, and Gibbs free energy.
  • In JEE Advanced, thermodynamics typically has a weightage of 6–8%.

Q2. What chapters have more weightage in the JEE Mains?

Answer: JEE Mains varies slightly every year, but certain chapters from Physics, Chemistry, and Mathematics are consistently given higher weightage.

Check: JEE Main 2025 Chapter Wise Weightage

Subject Chapter Weightage (%) Topics Covered
Physics Mechanics (Kinematics, Laws of Motion) 15–20% Motion, Newton's laws, work-energy theorem, conservation of momentum, circular motion, rotational motion.
Physics Electricity and Magnetism 10–15% Electrostatics, current electricity, magnetism, electromagnetic induction, alternating current (AC).
Physics Optics 8–10% Reflection, refraction, lenses, optical instruments, wave optics.
Chemistry Physical Chemistry (Thermodynamics, Gaseous State, Chemical Kinetics) 12–15% Laws of thermodynamics, ideal gas laws, entropy, reaction rates, Arrhenius equation.
Chemistry Inorganic Chemistry (Periodic Table, Coordination Compounds) 10–12% Trends in the periodic table, chemical bonding, d-block elements, isomerism in coordination compounds.
Chemistry Organic Chemistry (Aromatic Compounds, Hydrocarbons, Polymers) 8–10% Benzene derivatives, functional groups, nomenclature, reactions of alkenes, alkynes, and polymers.
Mathematics Algebra (Quadratic Equations, Complex Numbers) 12–15% Roots of equations, polynomial equations, properties of complex numbers, binomial theorem.
Mathematics Calculus (Differentiation, Integration) 15–20% Limits, continuity, differentiation, definite and indefinite integrals, applications of integrals.
Mathematics Coordinate Geometry (Straight Lines, Circles) 8–10% Equation of straight lines, slopes, distance between points, circle equations, tangents, and normal.
Mathematics Probability and Statistics 6–8% Permutation, combination, probability, mean, median, standard deviation.

Q3. Is scoring 150 marks in JEE Mains easy?

Answer: Scoring 150 marks in JEE Mains is possible with proper preparation, but it's not a cakewalk. It can be simple or difficult based on the year, but 150 will broadly fall under moderate to difficult as per difficulty levels.

  • High-Weightage Topics: For scoring 150, the candidate must prioritize the high-weightage topics in JEE Main such as Mechanics, Thermodynamics, and Calculus.
  • Consistency and Practice: Practice regularly improves the speed and accuracy, which is extremely crucial in order to secure high marks in JEE Mains.
  • Time Management: Time management is essential at the time of the exam. Attempt questions for which you are most sure first, and don't waste much time on a single question.
  • Conceptual Clarity: To have a lucid understanding of fundamental concepts facilitates your comprehension of the question when you are in the exam room.

Also Check: How to Prepare for JEE Main?